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자료유형
학술저널
저자정보
Hyun Ho Lee (Pusan National University) Chang Oh Hong (Pusan National University)
저널정보
한국토양비료학회 한국토양비료학회지 한국토양비료학회지 제48권 제6호
발행연도
2015.12
수록면
634 - 640 (7page)

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Chelating agents have been proposed to improve the efficiency of phytoextraction of heavy metal hyperaccumulator. However, little studies to elucidate mechanism of chelating agents to increase cadmium(Cd) extractability have been conducted. The objectives of this study were to evaluate effect of different chelating agents on Cd extractability and to determine mechanism of Cd mobilization affected by these agents. An arable soil was spiked with inorganic Cd (CdCl₂) to give a total Cd concentration of 20 mg Cd kg<SUP>-1</SUP>. Ethylenediaminetetraacetic acid (EDTA) and citric acid (CA) were selected and mixed with the arable soil at the rates of 0 and 5 mmol kg<SUP>-1</SUP>. The mixture soils were incubated at 25°C for 4 weeks in dark condition. Concentration of F1 Cd fractions (water soluble) significantly increased with addition of EDTA but did not changed with addition of CA. Especially; concentration of F5 Cd fractions (residual) significantly increased with addition of CA. Increase in water soluble with EDTA might be attributed to complexation of Cd and EDTA. Dissolved organic carbon concentration significantly increased with EDTA addition, but did not with CA implying that considerable amount of CA was decomposed to inorganic carbon by microorganism. Log activity of carbonate (CO₃<SUP>2-</SUP>) which might be generated from CA increased with addition of CA. Increase in residual Cd fraction might be due to precipitation of Cd as CdCO₃. As a result, EDTA was effective in increasing Cd extractability, by contrast CA had significant effect in reducing Cd extractability.

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Introduction
Materials and Methods
Results and Discussion
Conclusion
References

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UCI(KEPA) : I410-ECN-0101-2016-521-002207217