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논문 기본 정보

자료유형
학술저널
저자정보
M. A. Matin (Bangladesh University of Engineering and Technology) M. N. Hossain (Bangladesh University of Engineering and Technology) M. M. Islam (Dhaka University of Engineering and Technology) M. A. Hakim (Bangladesh University of Engineering and Technology) M. F. Islam (Bangladesh University of Engineering and Technology)
저널정보
한국전기전자재료학회 Transactions on Electrical and Electronic Materials Transactions on Electrical and Electronic Materials 제22권 제3호
발행연도
2021.1
수록면
243 - 249 (7page)

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In this paper, optical and ferroelectric properties were investigated for gadolinium, Gd3+ (5 at.%) and chromium, Cr3+ (0?8at.%) co-doped of BiFeO3 . Chemical solution deposition (CSD) method was employed as compatible device fabrication technology to synthesize Gd and Cr co-doped multiferroic BiFeO3 (Bi0.95Gd0.05Fe1?xCrxO3 with x = 0?0.08). X-ray diffraction (XRD) analysis confirmed a well-defined crystalline phase with a tendency towards structural change from rhombohedral to orthorhombic symmetry. Crystallite size was found to reduce substantially from 34 to 13.5 nm with increasing the doping concentration of Cr3+ . The field emission scanning electron microscopy (FESEM) demonstrated a significant reduction in grain size of doped BiFeO3 compared to un-doped one following the trend obtained from XRD results. Ferroelectric nature of samples was obtained from polarization versus electric field measurements. Improved ferroelectric order was displayed in co-doped BiFeO3 with a maximum remnant polarization of 0.23 μ C?cm2 . Diffuse reflectance measurement by UV?Vis?NIR spectroscopy of Gd 3+ and Cr3+ co-doped BiFeO3 has shown a significant reduction in the optical band-gap energy (Eg) to 1.71 eV compared to 2.03 eV of pure BiFeO 3 counterpart.

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