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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 발행연도
- 2015.2
- 수록면
- 21 - 27 (7page)
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초록· 키워드
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Hydrogen production from commercial diesel fuels is an attactive option for energy generation purpose due to the low cost and good availability of diesel fuels. However, in order to utilize commercial diesel fuels, the sulfur contents must be removed down to approximately 0.1 ppm level to protect the fuel cell catalysts from poisoning. Commercial catalysts CoMo/Al₂O₃ and NiMo/Al₂O₃ were tested for HDS (Hydrodesulfurization) of model diesel and commercial diesel. The experimental conditions were 250-400 °C and LHSV (Liquid Hourly Space Velocity) 0.27-2.12 hr-1. NiMo/Al₂O₃ was found to be more effective than CoMo/Al₂O₃ in removing sulfur from model diesel. Based on the experimental results of model diesel, commercial diesel fuel purchased from a local petrol station was tested for HDS using NiMo/Al₂O₃. The GC-SCD (Gas Chromatography Sulfur Chemiluminescence Detector) results showed that the DMDBT (Dimethyldibenzothiophene) derivatives were fully removed from the commercial diesel fuel proving that HDS with NiMo/Al₂O₃ is technically feasible for industrial applications.
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등록된 정보가 없습니다.
참고문헌 (9)
참고문헌 신청
I. Kang / 2006 / Autothermal reforming study of diesel for fuel cell application / Journal of Power Sources 159:1283~1290
B. Alsolami / 2011 / On-site low-pressure diesel HDS for fuel cell applications: Deepening the sulfur content to ⩽1 ppm / Fuel 90:3021~3027
C. Song / 2003 / An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel / Catalysis Today 86:211~263
C. Song / 2003 / New design approaches to ultra-clean diesel fuels by deep desulfurization and deep dearomatization / Applied Catalysis B:Environmental 41:207~238
X. Ma / 1994 / Hydrodesulfurization reactivities of various sulfur compounds in diesel fuel / Industrial & Engineering Chemistry Research 33:218~222
B. Alsolami / 2011 / On-site low-pressure diesel HDS for fuel cell applications: Deepening the sulfur content to ⩽1 ppm / Fuel 90:3021~3027
C. Song / 2003 / An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel / Catalysis Today 86:211~263
C. Song / 2003 / New design approaches to ultra-clean diesel fuels by deep desulfurization and deep dearomatization / Applied Catalysis B:Environmental 41:207~238
X. Ma / 1994 / Hydrodesulfurization reactivities of various sulfur compounds in diesel fuel / Industrial & Engineering Chemistry Research 33:218~222
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