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The Sulfur-Iodine (SI) thermochemical hydrogen production process of a closed cycle consists of three sections, which are so called the Bunsen reaction section, the H<sub>2</sub>SO<sub>4</sub> decomposition section and the HI decomposition section. To identify the role of oxygen that can be supplied to the Bunsen reaction section via the H<sub>2</sub>SO<sub>4</sub> decomposition section, Bunsen reactions with a SO<sub>2</sub>, SO<sub>2</sub>-O<sub>2</sub> mixture and SO<sub>2</sub>-N<sub>2</sub> mixture as feed gases were carried out using a stirred reactor in the presence of I<sub>2</sub>/H<sub>2</sub>O mixture. As the results, the amounts of I<sub>2</sub> unreacted under the feed of mixture gases were higher than those under the feed of SO<sub>2</sub> gas only, and the amount of HI produced was relatively decreased. The results of Bunsen reaction using SO<sub>2</sub>-O<sub>2</sub> mixture were similar to those using SO<sub>2</sub>-N<sub>2</sub> mixture. It may be concluded that an oxygen in SO<sub>2</sub>-O<sub>2</sub> mixture has a role as a carrier gas like a nitrogen in SO<sub>2</sub>-N<sub>2</sub> mixture. The effects of oxygen were decreased with increasing temperature and decreasing oxygen content in SO<sub>2</sub>-O<sub>2</sub> mixture.

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