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The Sulfur-Iodine (SI) thermochemical hydrogen production process is one of the most promising thermochemical water splitting technologies. In the integrated operation of the SI process, the O₂ produced from a H₂SO₄ decomposition section could be supplied directly to the Bunsen reaction section without preliminary separation. A HI<sub>x</sub> (I₂+HI+H₂O) solution could be also provided as the reactants in a Bunsen reaction section, since the sole separation of I₂ in a HI<sub>x</sub> solution recycled from a HI decomposition section was very difficult. Therefore, the Bunsen reaction using SO₂-O₂ mixture gases in the presence of the HI<sub>x</sub> solution was carried out to identify the effect of O₂. The amount of I₂ unreacted under the feed of SO₂-O₂ mixture gases was little higher than that under the feed of SO₂ gas only, and the amount of HI produced was relatively decreased. The O₂ in SO₂-O₂ mixture gases also played a role to decrease the amount of a impurity in HI<sub>x</sub> phase by only striping effect, while that in H₂SO₄ phase was hardly affected.

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