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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한국진공학회(ASCT) Applied Science and Convergence Technology Applied Science and Convergence Technology Vol.28 No.5
- 발행연도
- 2019.9
- 수록면
- 169 - 172 (4page)
- DOI
- 10.5757/ASCT.2019.28.5.169
이용수
초록· 키워드
오류제보하기
As ionic conductivities are related to the intrinsic structural features of materials, they are useful for elucidating structural changes. Herein, the ionic conductivities of crystals of NaBH₄, KBH₄, and their mixtures are determined for the first time. The melting and decomposition temperatures of various compositions are also measured. Thermal studies indicate that both the hydrides are well-mixed chemically, which is accomplished through a solid-state reaction using a simple ball milling process. The melting temperatures of Na<SUB>1-x</SUB>K<SUB>x</SUB>BH₄ complexes show large negative departures from linearity likely due to the formation of a new structural phase such as rhombohedral NaK(BH₄)₂. However, the ionic conductivities of Na1<SUB>-x</SUB>K<SUB>x</SUB>BH₄ complexes exhibit only small deviations from linearity with varying x values. The Na-rich samples of Na<SUB>1-x</SUB>K<SUB>x</SUB>BH₄ exhibit fast ion conduction behaviors and the ionic conductivity of 3×10<SUP>-3</SUP> Scm<SUP>-1</SUP> is obtained at approximately 50 ℃ below the melting point.
목차
ABSTRACT
Ⅰ. Introduction
Ⅱ. Experimental
Ⅲ. Results and discussion
Ⅳ. Summary
References
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UCI(KEPA) : I410-ECN-0101-2019-420-001277531