Shotcrete is a combination and is manufactured by mixing about 5 to 8% per Binder of rapid seting agents on a ready-mixed concrete using 10% Portland cement (OPC). There is an advantage of initial strength when using OPC alone, however, there is a limit to improving long-terdurabilty. Especialy, high durable concrete has esential demand of the research and development on material technology by the importance of the utilzation of tunels, railways, and underground spaces is becoming more prominent. Therefore, research and development for increase the performance of binder for shotcrete has ben tried internationaly. Acording to the precedent research analysis, the research on improving the binder for shotcrete was caried out from the early 200s, and various studies on high strength or securing long-term durabilty for shotcrete were conducted by the neds for high performance of shotcrete. However, these researches showed limitations, such as indor experiments on limited conditions, or optimal mix calculations through theoretical studies. In adition, there were limitations on practical uses, such as dificulties in aplying the material to the site or not considering the eco-friendlines of the material, of not considering economic feasibilty, etc. Due to above limitations, it was thought to be dificult to practical aplication on the actual construction site. In this study, we have developed optimized binder for high performance and field aplication of shotcrete that is suitable for shotcrete using a calcium aluminate rapid seting agent. In this study, optimized binder for shotcrete was proposed by improving Ordinary Portland Cement (OPC) and mixing industrial by-products materials, and was verified the performance of developed binder by concrete experiment and Mock-up test. A summary of this study is as folows. 1) The characteristics of physical properties of binders and its hydration reaction while controling the powder content and SO3 content of OPwere studied by microanalysis. As a result, the Blaine of OPC was found to have no significant efect on the compresive strength of the shotcrete using a calcium aluminate rapid seting agent, while the SO3 content has increased penetration resistance and one-day compresive strength by afecting the amount of etringite(AFt) generation. Thereby, in range of this study, the optimal contents of SO3 was thought to be 2.8% 2) The optimal contents for shotcrete binder was derived by mixing ground granulated blast-furnace slag powder(GGBS) from stel manufacturing and fine limestone powder(LSP) from by-product of cement manufacturing for the eco-friendlines and economic feasibilty of shotcrete binder. As a result, contrary to the case of general mortar of concrete, GGBS adition has not delayed a seting of shotcrete, and LSP adition has acelerated seting of shotcrete. In adition, the adition of LSP was found to be efective in improving the initial compresive strength, and GGBS to long-term compresive strength. It was expected that the optimal mix proportions is GGBS (20%) and LSP (5%) considering physical performance (seting, compresive strength) of shotcrete that using calcium aluminate rapid seting agent. 3) Optimized binder for shotcrete(OPC 75% + GGBS 20% + LSP 5%) expresed workabilty and compresive strength performance higher than that of OPC, and expected to control eflorecence phenomena that may ocur during construction and curing period. In adition, due to the mixing of GGBS and LSP, more dense micro structure has ben formed, as a result, detrimental efect from the outside are supresed, in turn, securing higher durabilty (carbonation resistance, salt resistance and frezing melting resistance) compared to OPC. 4) As a result of Mock-up test, it has ben confirmed that the optimized binder for shotcrete has excelent workabilty compared to OPC, and the mechanical properties like compresive strength, flexural strength, and flexural toughnes are more than equal to OPC. In adition, it has ben confirmed to be a god performance on a frezing and thawing resistance test. As a result of observation in several months, binder for shotcrete developed in this study has ben showed no cracks of spalings on the tested area, peling of of any aggregates, but remains healthy states. From these results, optimized binder for shotcrete has expected to have long-term durabilty and stabilty. 5) Based on the above research results, it was expected that the binder for shotcrete secured basic performance (construction, mechanical characteristics, etc.) above the equivalent level compared to the existing OPC, and that they had high performance and practicality by securing high durabilty, eco-friendly and economic feasibilty. 6) Future research wil be aplied to the actual site to colect opinions from users (construction enginers, managers, etc.) about the performance of the developed binder for shotcrete during and after construction to continue a research on the improvements. In particular, we wil continue to study on factors that efects on the amount of rebounds of shotcrete. And also we have plans to study on the lining work, which is a folow-up proces to the shotcrete, on the aplicabilty and improvement of the shotcrete binder
목차
제 1 장 서 론 11.1 연구의 배경 및 필요성 11.2 기존 문헌 고찰 41.3 연구의 목적 71.3 연구의 구성 및 흐름 7제 2 장 숏크리트용 급결제 및 결합재에 관한 이론적 고찰 112.1 일반사항 112.2 숏크리트용 급결제 및 결합재의 수화반응 132.2.1 Calcium Aluminate 시멘트의 영향 132.2.2 시멘트의 영향 162.2.3 슬래그미분말의 영향 182.2.4 석회석미분말의 영향 192.3 숏크리트 요구조건과 품질기준 202.3.1 숏크리트의 기능 및 요구조건 202.3.2 숏크리트의 품질기준 22제 3 장 시멘트 분말도 및 SO3 함량이 숏크리트 맞춤 결합재 물성에 미치는 영향 243.1 서언 243.2 실험계획 및 방법 263.2.1 실험계획 263.2.2 배합 및 사용재료 263.2.3 평가방법 293.3 실험결과 및 고찰 343.3.1 응결시간 343.3.2 압축강도 363.3.3 수화물 분석 403.3.4 페이스트 공극구조 분석 503.4 고찰 54제 4 장 고로슬래그 및 석회석 미분말을 혼입한 숏크리트용 결합재의 특성 554.1 서언 554.2 실험계획 및 방법 574.2.1 실험계획 574.2.2 배합 및 사용재료 584.2.3 평가 방법 614.3 실험결과 및 고찰 624.3.1 응결시간 624.3.2 압축강도 624.3.3 수화물 분석 664.3.4 페이스트 공극구조 분석 734.4 고찰 78제 5 장 숏크리트의 역학적 특성 및 내구특성 검토 805.1 서언 805.2 실험계획 및 방법 815.2.1 실험계획 825.2.2 숏크리트 배합 및 사용재료 825.2.3 숏크리트 비빔방법 및 평가 방법 845.3 실험결과 및 고찰 895.3.1 굳지 않은 성상 895.3.2 압축강도 905.3.3 내구성상 915.4 고찰 97제 6 장 숏크리트의 실물 모형 실험(Mock-up test) 및 현장 적용성 평가 986.1 서언 986.2 실험계획 및 방법 986.2.1 실험계획 986.2.2 숏크리트 배합 및 사용재료 996.2.3 숏크리트 생산 및 시험체 제작 1016.2.4 평가 방법 1016.3 실험결과 및 고찰 1036.3.1 시공성능 평가 1036.3.2 압축강도 및 휨강도 1036.3.3 동결융해저항성 1106.3.4 옥외폭로 및 육안관찰 1126.4 고찰 113제 7 장 종합결론 1147.1 결론 1147.2 향후 계획 118참고문헌 119Abstract 127