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논문 기본 정보

자료유형
학위논문
저자정보

김태선 (전북대학교, 전북대학교 일반대학원)

지도교수
백기태
발행연도
2021
저작권
전북대학교 논문은 저작권에 의해 보호받습니다.

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Decontamination of radioactive materials in the soil during the decommissioning of nuclear facilities is a challenging issue. Among the radioactive materials, cesium (Cs) is the most concerning radionuclides due to the inherent characteristics like long half-life time and high affinity with clay minerals. A process is required to treat the soil contaminated with radioactive materials generated during decommissioning the nuclear facilities. Remediation of Cs-contaminated soil is carried out to reach the feasibility of desorption of Cs from the soil and reduce the radioactive wastes. We proposed the “Extraction-selective adsorption-disposal” process as a method to treat Cs-contaminated soil. First in the extraction step, using soil washing, Cs+ attached to the soil could be separated into the solution by ion exchange. Among the extraction agents tested in this study, KCl showed relatively better extraction performance for Cs+, that is, 30 and 40 % from soil 1 and soil 2, respectively. However, the extraction of Cs+ by KCl is not enough to meet the decontamination goal, and enhanced extraction is required. The hydrothermal extraction and 3 times multi-step extraction were proposed to enhance the extraction of Cs+ and increased up to 70 %. The selective adsorption of Cs+ from the extracted solution was performed to figure out if Cs+ can be selectively removed from the wastewater of the extraction process in the presence of a high concentration of KCl. However, unfortunately, the presence of K+ hindered the adsorption of Cs+ onto adsorbents due to the structural similarity of the two ions. Especially, the high concentration of K+ inhibited the adsorption of Cs+ greatly even onto the Prussian blue modified zeolite. In both extraction and selective adsorption step, K+ acts as an important cation to desorb Cs+ from the soil and inhibit the adsorption of Cs+ onto zeolite.

목차

Chapter 1. Overall Introduction 1
1.1. Decommissioning nuclear power plants and radioactive materials 1
1.2. Characteristics of cesium 3
1.3. Treatment methods of Cs-contaminated soil 5
1.4. Adsorbents 7
1.4.1. Zeolite 8
1.4.2. Prussian blue 10
1.4.3. Composite of Zeolite and Prussian blue 11
1.5. Disposal of radioactive wastes 12
1.6. Research objectives 13
Chapter 2. Materials and Methods 15
2.1. Materials 15
2.1.1. Soil washing 15
2.1.2. Selective adsorption 16
2.2. Methods 17
2.2.1. Extraction step 17
2.2.1.1. Experimental methods 17
2.2.1.2. Normal soil washing 18
2.2.1.3. Hydrothermal treatment 19
2.2.1.4. Multi-step extraction 20
2.2.2. Selective adsorption 22
2.2.2.1. Selective adsorption characteristics of Cs in the presence of cations 22
2.2.2.2. Prussian blue modified zeolite 23
2.2.2.3. Adsorption of Cs+ using Prussian blue modified zeolite 24
Chapter 3. Results and Discussions 25
3.1. Extraction step 25
3.1.1. Properties of the soil 25
3.1.2. Screening test of extraction step 28
3.2. Enhanced treatment 33
3.2.1. Hydrothermal treatment 34
3.2.2. Multi-step extraction 38
3.3. Selective adsorption 46
3.3.1. Selective adsorption characteristic of Cs coexists with cations 46
3.3.2. Adsorption selectivity of Cs on Prussian blue modified zeolite 48
Chapter 4. Conclusions 50
References 52

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