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학위논문
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박민주 (창원대학교, 창원대학교 대학원)

지도교수
서규태
발행연도
2019
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창원대학교 논문은 저작권에 의해 보호받습니다.

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이 논문의 연구 히스토리 (4)

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This study focuses on the membrane filtration characteristics of food waste anaerobic digestion liquid for anaerobic membrane bioreactor (AnMBR) application. The digestion liquid was taken from methane forming reactor of a semi-pilot scale 2 phase anaerobic digestion system for food waste treatment. Membrane filtration of the liquid was carried out using MF, UF and NF to select an appropriate membrane. The suspended and total solid concentration of the digestion liquid were 25,467mg/L and 29,371 mg/L, respectively containing the particle size between 0.5 and 700 ㎛. Average flux of the membranes were 1.7, 1.7 and 0.8 L/m2·h·bar for MF, UF and NF in a dead end filtration, respectively. Almost complete flux recovery was observed in three times filtration of the UF membrane. This was comparable to MF (67% recovery) and NF (89% recovery) membrane. Volatile solid in the liquid was a major reason of the flux decline of the membranes. In a simulated cross flow filtration in a stirred cell which a shear force was given on the membrane surface, the flux of the UF membrane was significantly increased to 8.3L/m2·h·bar while those of the MF and NF membranes showed little improvement. The cake and gel layer resistance (Rc+Rg) was dominant parameter for the flux decline of all the membranes. It is considerable that MF was somewhat higher in pore plugging resistance (Rp) making less recovery of the flux by physical cleaning. Since NF membrane had high membrane resistance (Rm), UF membrane was considered as the most suitable for application to the anaerobic digestion liquid filtration in AnMBR process. Cross flow filtration was carried out for the UF membrane in a flat plate module. Average flux was slightly decreased from 19.86 L/m2·h·bar to 18.54 and 17.21 L/m2·h·bar at 3 times filtration with 4 hours each. The flux recovery was 93% and 85% by two times physical cleaning removing the cake and gel layer on the membrane. However there was fouling in the membrane pore requiring chemical cleaning in extended period of filtration. It was found by chemical cleaning that the fouling substances were carbohydrate and protein, fiber, salt, struvite, etc. remaining on the surface and pores of membrane after removing the cake layer. The membrane filtration process was designed according to the size of the semi-pilot plant of which treatment capacity is 5 kg/d of food waste. The required UF membrane area was 0.035 m2 in flat plate module. The suggested operation pressure and cross flow velocity was 1 bar and 0.24 m/s, respectively. Conclusively the UF membrane filtration system could be applicable to the food waste anaerobic digestion system to prolong SRT in the methanogenic reactor for enhanced biogas production with higher methane content.

목차

Ⅰ. 서 론 ··························································································································1
1.1 연구 배경 ·············································································································1
1.2 연구 목적 및 범위·····························································································3
Ⅱ. 이론적 배경 ·············································································································4
2.1 혐기성 소화·········································································································4
2.1.1 혐기성 소화 원리························································································4
2.1.2 음식물 쓰레기의 혐기성 소화 ································································6
2.1.2 막 결합형 혐기성 소화 (AnMBR) ·························································7
2.2 막여과 공정·········································································································9
2.2.1 막여과의 정의 ······························································································9
2.2.2 막의 분류······································································································9
2.2.3 막의 여과 방식··························································································10
2.2.4 Flux ··············································································································11
2.2.5 막의 오염····································································································11
2.2.6 막 여과 저항 ······························································································13
Ⅲ. 실험재료 및 실험방법 ························································································14
3.1 실험재료 ···········································································································14
3.1.1 여과 대상 시료 ··························································································14
3.1.2 분리막 ··········································································································15
3.2 실험장치 구성 및 운전···················································································16
3.2.1 Stirred cell ································································································16
3.2.2 Cross-flow module ·················································································16
3.3 분석방법·············································································································18
3.3.1 대상 시료의 성상분석 ··············································································18
3.3.2 Flux decline and recovery rate ·····························································18
3.3.3 막 여과 저항 ····························································································19
3.3.4 파울링 유발 물질······················································································20
Ⅳ. 결과 및 고찰 ·········································································································21
4.1. 소화액의 수질특성 ··························································································21
4.1.1 유기물 및 고형물······················································································21
4.1.2 입도 분석····································································································22
4.2. 혐기성 소화 슬러지의 막 여과 특성··························································23
4.2.1 막 종류에 따른 여과 특성 비교 ··························································23
4.2.2 여과방식에 따른 Flux 비교 ············································································28
4.2.3 막 여과 저항 ······························································································31
4.3 평판형 모듈에서의 UF 막 여과 특성·························································33
4.3.1 Flux decline and recovery ······································································33
4.3.2 투과수의 성상 분석 ··················································································35
4.3.3 막 오염 물질 ····························································································37
4.3.4 막 세척 방안 ······························································································43
4.4 AnMBR 구성을 위한 막 여과 공정 설계 ··················································45
4.4.1 막 모듈 설계 ······························································································45
4.4.2 운전에 필요한 요소 ··················································································46
Ⅴ. 결론 ··························································································································49
참 고 문 헌 ···················································································································51
Abstract ························································································································59

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