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논문 기본 정보

자료유형
학위논문
저자정보

남윤미 (충남대학교, 忠南大學校 大學院)

지도교수
이진홍
발행연도
2018
저작권
충남대학교 논문은 저작권에 의해 보호받습니다.

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In the present study, the BOD and T-N concentrations of dewatered cake required to estimate the GHG emissions from the sewage treatment were estimated from the TS and VS concentrations in dewatered cake.
The regression analysis between (TS × VS) vs BOD and (TS × VS) vs. T-N of digested sludge was studied to derive the methods to estimate BOD and T-N concentrations from TS and VS concentrations of dewatered cake. The optimal regression equation derived from regression analysis was as follows: y=152425x (R2=0.969, p<0.05) for BOD and y=128378x (R2=0.970, p<0.05) for T-N.
As a result of verifying the applicability of the regression equation to the digested sludge of the period not included in the regression analysis, the differences between the measured and estimated concentration data (derived by regression equation) were within the standard deviation of measured concentration. These results indicate that it is possible and appropriate to estimate the BOD and T-N concentrations of sewage sludge from (TS × VS). The reason for the concentration difference in BOD is that (TS × VS) does not accurately reflect the VS fraction in the TS. For T-N, the constant of the regression equation is set to zero, which tends to somewhat decrease the inorganic nitrogen content.
The results of the verification for the applicability of the regression equation to dewatered cake suggested that the differences between the BOD and T-N estimated by the regression equation and those by the mass balance were considerably large. The main reason for the differences can be that the method of estimation by the material balance is greatly affected by the filtrate of dewatering facility. However, the differences did not significantly affect the total GHG emissions in the municipal waste sector.
The results of the verification of the applicability of the regression equation to other sewage treatment plants demonstrated that the differences between the estimation concentration by the regression equation and the actual measurement concentration were inconsistent according to the sewage treatment plant. Therefore, it can be suggested that the application of the regression equations to other sewage treatment plants was not appropriate. However it appears to be possible to derive the plant specific regression equations according to this study method and to reflect the equations to the estimation of GHG emissions.
From the results outlined above, it can be concluded that (TS × VS) of sewage sludge has sufficient correlation to represent BOD and T-N concentration, and that BOD and T-N concentrations can be estimated with (TS × VS) as an independent variable.
In this study, we present BODsl = 152425 (TS × VS) and T-Nsl = 128378 (TS × VS) as the method to estimate BOD and TN concentration of dewatered cake by (TS × VS) in sewage treatment plant A. We also propose the following new modified formula to estimate GHG emissions by sewage treatment plants that reflects the method of estimating BOD and T-N concentrations by the (TS × VS) of the dewatered cake at sewage treatment plant A.

CH4={BODin×Qin-BODout×Qout-152425(TS×VS)sl×Qsl}×0.000001×EF-R

N2O={T-Nin×Qin-T-Nout×Qout-128378(TS×VS)sl×Qsl}×0.000001×EF×1.571

목차

1. 서 론 1
2. 배 경 7
2.1. 하수처리공정의 개요 7
2.2. 하수처리에 의한 온실가스 11
2.2.1. 온실가스의 종류 및 배출원인 11
2.2.2. 하수처리의 온실가스 산정방법 13
2.3. 하수처리 시설운영 관련 시험항목 26
2.4. 온실가스 배출량 산정에 필요한 시험항목 28
2.5. 탈수케이크의 주요 시험항목 29
2.5.1. TS(총 고형물, Total Solid) 31
2.5.2. VS(휘발성 고형물, Volatile Solid) 32
2.6. 회귀분석(regression analysis) 34
2.6.1. 회귀분석의 가정 36
2.6.2. 단순회귀방정식의 적합도 및 유의성 분석 40
2.6.3. 회귀방정식의 진단 43
3. 연구방법 53
3.1. 데이터 수집 55
3.1.1. 대상 하수종말처리장 55
3.1.2. 수집 데이터의 종류 및 기간 56
3.2. 소화슬러지의 (TS×VS)와 BOD/(TS×VS)와 T-N 농도 간 회귀분석 60
3.2.1. 데이터 필터링 60
3.2.2. 회귀분석 64
3.3. 회귀방정식의 검증 66
3.3.1. 회귀분석 미포함 기간에 대한 적용가능성 검증 66
3.3.2. 회귀방정식의 탈수케이크에 대한 적용 가능성 검증 71
3.3.3. 회귀방정식의 타 하수종말처리장에 대한 적용가능성 검증 72
3.4. 회귀방정식을 반영한 하수처리 온실가스 배출량 산정방법론 도출 75
4. 결과 및 고찰 77
4.1. 소화슬러지의 (TS×VS)와 BOD/(TS×VS)와 T-N 농도 간 회귀방정식 도출 결과 77
4.1.1. (TS×VS)와 BOD 농도 간 회귀분석 77
4.1.2. (TS×VS)와 T-N 농도 간 회귀분석 87
4.2. 회귀방정식의 검증 결과 100
4.2.1. 회귀분석 미포함 기간에 대한 적용 가능성 검증 결과 100
4.2.2. 탈수케이크에 대한 적용 가능성 검증 결과 102
4.2.3. 타 하수종말처리장에 대한 적용 가능성 검증 결과 111
4.2.4. 검증결과에 대한 종합평가 113
4.3. 탈수케이크 BOD, T-N 농도를 반영한 하수처리 온실가스 배출량 산정방법론 도출 결과 115
5. 결 론 117
참 고 문 헌 121
ABSTRACT 131

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