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논문 기본 정보

자료유형
학위논문
저자정보

임희섭, 콘크리트공학 (한양대학교, 한양대학교대학원)

지도교수
이한승
발행연도
2017
저작권
한양대학교 논문은 저작권에 의해 보호받습니다.

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이 논문의 연구 히스토리 (4)

초록· 키워드

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Electric Furnace Oxidizing slag (EOS) happens in the steelmaking process during refining process of pig iron. Based on literature reivew, no usage has been reported for the reason that EOS contains Free CaO, which causes expansiveness. Recently, application of technology on specification of EOS and Ladle Furnace slag led to establishment in Korean Standard (KS), so possibility of usage as aggregates for concretes has been proven. However, the fact that no standard about Free CaO has been listed on the KS causes no using as concrete aggregate and recycling in the form of low value such as road and roadbed. The standard and guideline on replacement with lack of aggregates and using as eco-friendly materials has been establishing in the foreign developed country.
EOS has high density with the value 3.0~3.8 ton/m3 and high unit volume when performing concrete mixing design. The concrete with high volume has been used for the heavy concrete and radiation shielding concrete, so a lot of researches has been carried out. However, these magnetite and barite are not being produced, and depend on imports. Recently, problems on imports of these materials from foreign countries causes replacement with plain concrete for radiation shielding concrete. Construction on thick concrete is being performed after formation with iron plate and lead plate, when pouring plain concrete.
Therefore, after the evaluation on the expansiveness of EOS is done and mechanical property for concrete aggregates is performed, the research on radiation shielding concrete with high value is needed.
On this study, possibility of development for radiation shielding concrete has been identified through performance of radiation shielding of EOS concrete after evaluation of safety against expansiveness of EOS.

(1) Suggestion of evaluation method on safety against expansiveness of EOS
To show the evaluation method on safety against expansiveness of EOS, KS standard is used for detailed analysis. For physical safety method, volumetric stability has been analyzed, and for chemical analysis method, method of CaO analysis has been investigated as followed KS.
For physical method, difference rate according to length change using sieve and mortar method with autoclave has been suggested. For chemical method, evaluation method of Free-CaO within EOS has been identified using Ethylene Glycol method, which is the method to figure out the amount of Free-CaO.

(2) Establishment of reliability on the evaluation method of safety against EOS''s expansiveness
① Through literature review, standard on change in amount of Free-CaO has been suggested according to change in temperature and time, and the amount of Free-CaO within cement and EOS has been evaluated using Ethylene Glycol method.
② Difference in contents of Free-CaO has been evaluated according to change in content of Free-CaO on each aging periods, and stockyard (1m depth difference between in and outside stocked slag).
③ The content evaluation of Free-CaO of EOS emitting EOS from 4 domestic steel companies (Hyundai steel, Dongkuk steel, Daehan steel, Kisco) has been done.

(3) Performance evaluation of mortar and concrete using EOS aggregate
The property of fresh concrete using EOS aggregate has been evaluated, and then, the evaluation of change in compressive strength according to replacement rate of EOS and unit volume has been done. Furthermore, compressive strength and micro analysis of mortar according to replacement rate with EOS has been performed.

(4) Performance of radiation shielding of radiation shielding concrete with EOS
Radiation shielding performance of EOS concrete, plain and magnetite concrete has been done through transmission test of X-ray and gamma to figure out the possibility of development of radiation shielding concrete using EOS.

목차

Contents
List of Figures
List of Tables
Abstract in Korean
1. Introduction
1.1 Research background and necessity
1.2 Research purpose and content
1.3 The composition of research
2. literature review
2.1 Quality property of EOS
2.1.1 Recycling and current situation of steel slag
2.1.2 Standard of electric furnace oxidation slag
2.1.3 Stabilization method of electric furnace slag
2.1.4 Expansion mechanism of electric slag
2.1.5 Safety evaluation test method of KS
2.1.6 Investigation of CaO analysis method of KS
2.1.7 Property of concrete with EOS
2.1.8 Current situation on using domestic electric furnace slag
2.1.9 Research trend on domestic electric furnace slag
2.1.10 Foreign research trend of EOS
2.2 Required performance and application example of radiation shielding concrete
2.2.1 The theory of radiation shielding
2.2.2 Maximum allowable dosage of radiation facility
2.2.3 Outline of radiation shielding concrete
2.2.4 Current situation on domestic nuclear facility
2.2.5 Example of facility with radiation shielding concrete
2.2.6 Domestic research trends on radiation shielding concrete
2.2.7 Foreign research trends on radiation shielding concrete
2.3 Summary of chapter 2
3. Evaluation experiment on safety against expansion of EOS
3.1 Introduction
3.2 Experimental plan
3.2.1 Evaluation method on physical safety of EOS
3.2.2 Evaluation method on chemical safety of EOS aggregate
3.3 Materials
3.3.1 XRD experiment of EOS, ERS, and CS
3.4 Experimental method
3.4.1 Sieve method using autoclave
3.4.2 Mortar method using autoclave
3.4.3 Quantitative evaluation method of Free-CaO within electric furnace oxidation slag using ethylene glycol method
3.5 Experimental results
3.5.1 Sieve test results using autoclave
3.5.2 Experiment results on mortar method using autoclave
3.5.3 Results of quantitative evaluation method of Free-CaO of electric furnace slag using ethylene glycol methods
3.6 Summary of chapter 3
4. Performance evaluation of mortar and concrete using electric arc furnace oxidation slag aggregate
4.1 Summary
4.2 Physical properties of concrete using electric arc furnace oxidation slag aggregate
4.2.1 Experimental plan
4.2.2 Materials
4.2.3 Measurement items and test methods
4.2.4 Test Results and Considerations
4.3 Performance Evaluation of Mortar Using Electric Arc furnace oxidation Slag Aggregate
4.3.1 Experimental plan
4.3.2 Measurement Items
4.3.3 Experimental Results
4.4 Summary of chapter 4
5. Performance evaluation of radiation shielding concrete using electric arc furnace oxidation slag aggregate
5.1 Summary
5.2 Experimental Plan
5.3 Materials
5.4 Measurement Items
5.5 Experimental Results
5.5.1 Test results of concrete
5.5.2 X-ray shielding performance
5.5.3 Gamma ray shielding performance
5.6 Summary of chapter 5
6. Conclusion
References
ABSTRACT
Acknowledgement
Declaration of Ethical Conduct in Research (in Korean)
Declaration of Ethical Conduct in Research (in English)

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