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Effects of Partial Substitution of Nitrate on the Superconducting Properties of TlSr₄Cu₂Oz(SO₄)
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NO₃ 가 부분치환된 TlSr₄Cu₂Oz(SO₄)계의 초전도특성

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Type
Academic journal
Author
Ho Keun Lee (강원대학교)
Journal
The Korean Physical Society New Physics: Sae Mulli Vol.70 No.11 KCI Accredited Journals SCOPUS
Published
2020.11
Pages
909 - 913 (5page)

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Effects of Partial Substitution of Nitrate on the Superconducting Properties of TlSr₄Cu₂Oz(SO₄)
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The effects of partial substitution of nitrate groups at the SO₄ sites on the superconducting properties of the TlSr₄Cu₂O<sub>z</sub>(SO₄)<sub>1-x</sub>(NO₃)<sub>x</sub> system have been investigated. X-ray diffraction data showed that the solubility limit of (NO₃) was about x = 0.35. The change in the solubility limit of oxyanion for sulfate was discussed in connection with the characteristics of the oxyanion species. Within the solubility limit, the introduction of the nitrate groups did not change significantly the transition temperature of the pristine TlSr₄Cu₂O<sub>z</sub>(SO₄) compound. However, we found that compared to the pristine compound, the introduction of the nitrate groups degraded the stability properties of the sample after annealing at 400℃ in Ar atmosphere.
#산화 음이온 초전도체 #NO₃ 치환 #안정도 #TlSr₄Cu₂O< #sub> #z< #/sub> #(SO₄)< #sub> #1-x< #/sub> #(NO₃)< #sub> #x< #/sub> #Oxyanion superconductors #Nitrate substitution #Stability

Contents

I. 서 론
II. 실 험
III. 실험결과 및 토의
IV. 결 론
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