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논문 기본 정보

자료유형
학술저널
저자정보
Sung-Yong Chun (Mokpo National University)
저널정보
한국부식방식학회 Corrosion Science and Technology CORROSION SCIENCE AND TECHNOLOGY 제22권 제6호
발행연도
2023.12
수록면
393 - 398 (6page)
DOI
10.14773/cst.2023.22.6.393

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Properties of hafnium nitride (HfN) coatings are affected by deposition conditions, most often by the sputtering technique. Appropriate use of different magnetron sputtering modes allows control of the structural development of the film, thereby enabling adjustment of its properties. This study compared properties of HfN coatings deposited by direct current magnetron sputtering (dcMS), mid-frequency direct current magnetron sputtering (mfMS), and inductively coupled plasma-assisted magnetron sputtering (ICPMS) systems. The microstructure, crystalline, and mechanical properties of these HfN coatings were investigated by field emission electron microscopy, X-ray diffraction, atomic force microscopy, and nanoindentation measurements. HfN coatings deposited using ICPMS showed smooth and highly dense microstructures, whereas those deposited by dcMS showed rough and columnar structures. Crystalline structures of HfN coatings deposited using ICPMS showed a single δ-HfN phase, whereas those deposited using dcMS andmfMS showed a mixed δ-HfN and HfN 0.4phases. Their performance were increased in the order of dcMS < mfMS < ICPMS, with ICPMS achieving a value of 47.0 GPa, surpassing previously reported results.

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