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논문 기본 정보

자료유형
학술저널
저자정보
Kim Eunyoung (Technical Research Institute Korea Zinc Co. Ltd. Ulsan Republic of Korea) Ahn Taebum (Technical Research Institute Korea Zinc Co. Ltd. Ulsan Republic of Korea) Kim Tae-Young (Technology Institute Cosmochemical Co. Ltd. Ulsan Republic of Korea)
저널정보
한국자원공학회 Geosystem Engineering Geosystem Engineering Vol.25 No.3
발행연도
2022.12
수록면
143 - 149 (7page)
DOI
10.1080/12269328.2022.2119610

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This study provides a new leaching method for selective recovery of manganese from the spent NCM-based cathode active material of lithium-ion secondary batteries (LIBs). The recovery method involves the use of aqueous Mn(II) phase spontaneously generated in sulfate media as a reducing agent, in which Ni(III) and Co(III) are reduced to soluble species while Mn(II) precipitates as Mn(IV) oxides simultaneously. To optimize the process, the effects of time, temperature, and acid concentration on the leaching behavior were investigated. As a result, two-step successive leaching at an optimal condition was proposed, by which the dissolution efficiency of Co and Ni reached up to 99% and ~100%, respectively while Mn leaching was restricted to 15.5%. The leaching residue mainly consisted of manganese oxide (MnO2), containing Mn ~40%. The amount of Mn in the residue increased to ~70% by calcinating at 650 °C, which converted its phase into Mn2O3 and Mn3O4. Therefore, our two-step leaching technique will lead to the recovery of nearly all the contents of Li, Co, and Ni in addition to ~70% purity Mn as supplemental benefit from spent LIB materials without using any oxidants or reductants.

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