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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한양대학교 세라믹공정연구센터 Journal of Ceramic Processing Research Journal of Ceramic Processing Research 제18권 제11호
- 발행연도
- 2017.11
- 수록면
- 824 - 830 (7page)
- DOI
- http://dx.doi.org/
이용수
초록· 키워드
오류제보하기
Fe2O3, Ti, Fe, and TiCl3 were chosen as additives to increase the hydrogen absorption and release rates of Mg. Samples with compositions of 80 wt% Mg + 14 wt% Ni + 6 wt% Fe2O3 (named Mg-14Ni-6Fe2O3), 80 wt% Mg + 14 wt% Ni + 3 wt% Fe2O3 + 3 wt% Ti (named Mg-14Ni-3Fe2O3-3Ti), 80 wt% Mg + 14 wt% Ni + 2 wt% Fe2O3 + 2 wt% Ti + 2 wt% Fe (named Mg-14Ni-2Fe2O3-2Ti-2Fe), and 80 wt% Mg + 14 wt% Ni + 6 wt% TiCl3 (named Mg-14Ni-6TiCl3) were prepared by high-energy ball milling in hydrogen. The hydrogen absorption and release properties of the prepared samples were investigated and compared. The halide and nickel-added Mg, Mg-14Ni-6TiCl3, had larger quantities of hydrogen absorbed and released for 60 min and a larger initial dehydriding rate than the oxide and nickel-added Mg samples. In particular, the hydrogen absorption and release properties of Mg-14Ni-6TiCl3 were examined in more detail. The activation of Mg-14Ni-6TiCl3 was completed after two hydriding-dehydriding cycles (cycling between hydriding under 12 bar H2 at 593 K and dehydriding in vacuum at 623 K). Mg-14Ni-6TiCl3 had an effective hydrogen-storage capacity of about 5.2 wt%. At the third cycle, the sample released 1.05 wt% H for 2.5 min, 2.82 wt% H for 10 min, and 4.88 wt% H for 60 min.
목차
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참고문헌 (40)
참고문헌 신청
홍성현 / 2016 / Study on the Reactivity with Hydrogen of Planetary Ball Milled 90 wt% Mg+10 wt% MgH2: Analyses of Reaction Rates with Hydrogen and Microstructure / 대한금속·재료학회지 54(5):358~363
송명엽 / 2016 / Hydrogen Storage Characteristics of Metal Hydro-Borate and Transition Element-Added Magnesium Hydride / 대한금속·재료학회지 54(7):503~509
권성남 / 2016 / Hydrogen Storage and Release Properties of Transition Metal-Added Magnesium Hydride Alloy Fabricated by Grinding in a Hydrogen Atmosphere / 대한금속·재료학회지 54(7):510~518
J.J. Reilly / 1967 / Inorg. Chem 6(12):2220~2223
송명엽 / 2016 / Enhancement of Hydrogen Storage Characteristics of Mg by Addition of Nickel and Niobium (V) Fluoride via Mechanical Alloying / 대한금속·재료학회지 54(3):210~216
송명엽 / 2016 / Hydrogen Storage Characteristics of Metal Hydro-Borate and Transition Element-Added Magnesium Hydride / 대한금속·재료학회지 54(7):503~509
권성남 / 2016 / Hydrogen Storage and Release Properties of Transition Metal-Added Magnesium Hydride Alloy Fabricated by Grinding in a Hydrogen Atmosphere / 대한금속·재료학회지 54(7):510~518
J.J. Reilly / 1967 / Inorg. Chem 6(12):2220~2223
송명엽 / 2016 / Enhancement of Hydrogen Storage Characteristics of Mg by Addition of Nickel and Niobium (V) Fluoride via Mechanical Alloying / 대한금속·재료학회지 54(3):210~216
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