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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한국고분자학회 폴리머 폴리머 제46권 제4호
- 발행연도
- 2022.7
- 수록면
- 426 - 435 (10page)
- DOI
- 10.7317/pk.2022.46.4.426
이용수
초록· 키워드
오류제보하기
In this work, the synthesized nanoporous aluminum fumarate (Al_FA_A) metal organic framework (MOF) has been used as reactive filler for the bisphenol-A dicyanate (BADCy) resin system. The use of Al_FA_A is interesting due to the involvement of double bonds (fumarate) in triazine during polymerization. The thermal properties of the polymers formed with and without reactive filler were evaluated under different curing temperatures, prepolymerizations and post-polymerizations conditions. All the samples were characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and X-ray diffraction analysis (XRD) and Evolved gas analysis. On the contrary, the cure chemistry was determined by non-isothermal model free kinetic methods. This study provides a new path to utilize the MOFs as reactive nanoparticle fillers to obtain multifunctional materials.
목차
Abstract
Introduction
Experimental
Results and Discussions
Conclusions
References
참고문헌 (41)
참고문헌 신청
Hammerton, I. Chemistry and Technology of Cyanate Ester; Springer: Dordrecht, 1994.
Fink, J. K. Reactive Polymers Fundamentals and Applications; William Andrew Publishing: Norwich, 2006.
Laurence, W. M. The Effect of Long Term Thermal Exposure on Plastics and Elastomers; William Andrew Publishing: Norwich, 2014.
Clerici, C.; Gu, X. H.; Sung, L.; Forster, A. M.; Ho, D. L.; Stutzman, P.; Nguyen, T.; Martin, J. W. Effect of Pigment Dispersion on Durability of a TiO2 Pigmented Epoxy Coating During Outdoor Exposure. In Service Life Prediction of Polymeric Materials; Martin, J. W., Ryntz, R. A., Chin, J., Dickie, R. A., Eds.; Springer: New York, 2009; pp 475-492.
Guenthner, A. J.; Lamison, K. R.; Vij, V.; Reams, J. T.; Yandek, G. R.; Mabry, J. M. New Insights into Structure-Property Relationships in Thermosetting Polymers from Studies of Cocured Polycyanurate Networks. Macromolecules 2012, 45, 211-220.
Fink, J. K. Reactive Polymers Fundamentals and Applications; William Andrew Publishing: Norwich, 2006.
Laurence, W. M. The Effect of Long Term Thermal Exposure on Plastics and Elastomers; William Andrew Publishing: Norwich, 2014.
Clerici, C.; Gu, X. H.; Sung, L.; Forster, A. M.; Ho, D. L.; Stutzman, P.; Nguyen, T.; Martin, J. W. Effect of Pigment Dispersion on Durability of a TiO2 Pigmented Epoxy Coating During Outdoor Exposure. In Service Life Prediction of Polymeric Materials; Martin, J. W., Ryntz, R. A., Chin, J., Dickie, R. A., Eds.; Springer: New York, 2009; pp 475-492.
Guenthner, A. J.; Lamison, K. R.; Vij, V.; Reams, J. T.; Yandek, G. R.; Mabry, J. M. New Insights into Structure-Property Relationships in Thermosetting Polymers from Studies of Cocured Polycyanurate Networks. Macromolecules 2012, 45, 211-220.
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