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논문 기본 정보

자료유형
학술저널
저자정보
Tae-Kyoung Kim (University of California) Woo-Seok Choe (Seoul National University) Taeyeon Kim (Seoul National University) Seon-Ha Chae (Korea Water Resources Corporation) Yu Sik Hwang (Korea Institute of Toxicology) Kyung-Duk Zoh (Seoul National University)
저널정보
대한환경공학회 Environmental Engineering Research Environmental Engineering Research 제27권 제6호
발행연도
2022.12
수록면
124 - 132 (9page)

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초록· 키워드

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Because disinfectants have been essential during the COVID-19 pandemic, the global demand for benzalkonium chlorides (BACs) has significantly increased. BACs can inactivate coronaviruses, but are known as toxic. In this study, we investigated the adsorption mechanisms of BAC<SUB>12</SUB>, BAC<SUB>14</SUB>, and BAC<SUB>16</SUB> in water using powdered activated carbon (PAC). The effects of the reaction time, pH, and temperature on the adsorption kinetics of BACs were examined. The adsorption reaction followed pseudo-second-order kinetics, and better fitted to the Langmuir isotherm than the Freundlich isotherm. The best adsorption of BACs was achieved at neutral pH conditions. Thermodynamic analysis revealed that adsorption of BACs onto PAC is a spontaneous and endothermic process. Competitive adsorption experiments revealed that BACs with longer alkyl chains were adsorbed more effectively onto PAC than shorter alkyl chain BACs, implying that, while the electrostatic interaction is an important adsorption mechanism for BAC<SUB>12</SUB>, van der Waals interaction plays a more important role during the adsorption of BAC<SUB>14</SUB> and BAC<SUB>16</SUB>. Finally, we observed the partial detoxification (69%) BAC in adsorption treated water with PAC using a Microtox test.

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ABSTRACT
1. Introduction
2. Materials and Methods
3. Results and Discussion
4. Conclusions
References

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