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논문 기본 정보

자료유형
학술저널
저자정보
윤철우 (국립환경과학원) 엄남일 (국립환경과학원) 최효현 (국립환경과학원) 강영렬 (국립환경과학원) 전태완 (국립환경과학원) 신선경 (국립환경과학원)
저널정보
한국폐기물자원순환학회 한국폐기물자원순환학회지 한국폐기물자원순환학회지 제32권 제7호
발행연도
2015.1
수록면
675 - 685 (11page)

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초록· 키워드

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Phospho-gypsum (PG) is a by-product generated from wet process of phosphoric acid production. The recycling rate of PG is only fifteen percents for the recycling uses, such as cement retardant, gypsum board, plaster, functional fertilizer. In the result of pH analysis, PG, neutralizing gypsum, soil, and dredged soil were 3.5, 7.4, 8 to 8.8, and 7.8, respectively. In case of the electric conductivity (EC), PG, neutralizing gypsum, and soil were 2,990 μS/cm, 2,230 μS/cm, and 84 ~ 99 μS/cm, respectively. In heavy metal contents of PG, As and Cd could be measured under environmental standards in Korean Soil Environment Conservation Act. In inorganic elements of leaching PG, Ca and Na were 629 mg/ L and 13 mg/L, respectively, but As, Cd, and other elements were detected under the regulated levels in Korean Waste Management Act. Also, among inorganic elements in PG, the leaching ratio of Mg and Cd were 7.3%, 1.3% respectively. In neutralized PG, leaching ratio of Mg and Cu were 1.9%, 1.4% respectively compared with other elements. In sequential batch leaching test, the leaching concentrations of As and Cd were rapidly decreased after 2 days. F− and Ca were steadily decreased until 2 days and 8 days, respectively, and no more change since then. In case of SO4 2−, it fell at constant rate to 1,600 ~ 1,800 mg/L. As seen in Ca leaching curve relating to pH value, the leaching decreased with increasing pH.

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