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논문 기본 정보

자료유형
학술저널
저자정보
Xuejiao Liu (Beijing Forestry University) Qinfeng Zou (Beijing Forestry University) Tianhao Wang (Beijing Forestry University) Liping Zhang (Beijing Forestry University)
저널정보
성균관대학교 성균나노과학기술원 NANO NANO Vol.13 No.3
발행연도
2018.1
수록면
109 - 122 (14page)

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초록· 키워드

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Cellulose nanofibril (CNF) and graphene (GR) powder were added into polylactic acid (PLA)/ polypyrrole (PPy) composite films via a low-cost, eco-friendly, low-temperature, and in-situ polymerization synthesis, which obtain novel flexible and conductive polylacticacid-cellulose nanofibril-graphene/polypyrrole (PLA–CNF–GR/PPy) composite films. The CNF was embedded in the PLA matrix to enhance the mechanical properties. Remarkably, when a few GR (1%) powder was added, the tensile strength of composite films increased by 5.6%, respectively, compared with pure PLA–CNF, and increased by 17.6% compared with the PLA. The GR and CNF had a positive influence on mechanical properties of composite films. In addition, the PLA–CNF–GR/PPy composite films exhibited many unique properties when GR powder was introduced, including high thermal stability, and especially electrical conductivity. The electrical conductivity of the PLA–CNF–GR/PPy composite films increased from 0.12 to 1.06 S/cm as the content of GR powder increased from 0 to 10%. The PLA–CNF–GR-10/PPy also demonstrated excellent flexible stability, only 7.5% deviation after over 100 bending cycles. Furthermore, we designed and found that the exploration of a flexible solid-state supercapacitor assembled with PLA–CNF–GR-10/PPy composite electrodes had a capacitance of 30 F/g at a current density of 0.5 A/g. Although it was not quite as prominent as the capacitance, it provided an innovative means for preparing the conductive composite films. Based on these advantages the PLA–CNF–GR/PPy could be considered as sensors, flexible electrodes, and flexible displays. It also opens a new field of potential applications of biodegradable materials.

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