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Recently plating industry has a tendency to introduce a composite plating process to help reduce costs and simplify metal plating process. However, the treatability of a composite plating wastewater containing complexed heavy metals as nickel and zinc by conventional coagulation process has a limit. Therefore, the study focused on the effect of operation parameters on each system treatability performance in terms of nickel and zinc and organics, and then is to research the optimum process. The proposed processes were experimentally investigated in a combined system of the lab-scale advanced oxidation processes(AOPs) as Fenton or Fenton-like and Electrolysis-Fenton/Fenton-like with coagulation. The results indicated that all proposed processes in this study could be almost removed Zn completely and an electro-Fenton process with hydroxide precipitation was the best among these processes. In the field wastewater test of that process, a value of obtained results was observed with Ni 48.2mg/L to 10.3mg/L, Zn 126.7mg/L to 0.6mg/L, and CODMn is shown to be reduced from 2560mg/L to 230.4mg/L. The optimum operating condition for the electro-Fenton process was as follows; the electrolysis reaction time 10min, an applied current density of 3.74mA/cm2 at bipolar type reactor packed by granular activated carbon(GAC) and Fenton's reaction time 60min at the initial pH 5.0 and Fe(II)/H2O2 20mM/600mM.
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참고문헌 (15)
참고문헌 신청
정호진 / 2013 / 도금폐수의 시안 및 중금속 제거에 관한 연구 / 한국수처리학회지 21(2):47~57
Jong-su Kim / 2014 / The removal of organics and heavy metals in composite plating wastewater using advanced oxidation and coagulation processes
Shanhong Lan / 2012 / Treatment of wastewater containing EDTA-Cu(II) using the combined process of interior microelectrolysis and Fenton oxidation-Coagulation / Separation and Purification Technology 89:117~124
I. Kabdashi / 2009 / Complexing agent and heavy metal removals from metal plating effluent by electrocoagulation with stainless steel electrodes / Journal of Hazardous Materials 165:838~845
Fenglian Fu / 2009 / Fenton and Fenton-like reaction followed by hydroxide precipitation in the removal of Ni(II)from NiEDTA wastewater : A comparative study / Chemical Engineering Journal 155:769~774
Jong-su Kim / 2014 / The removal of organics and heavy metals in composite plating wastewater using advanced oxidation and coagulation processes
Shanhong Lan / 2012 / Treatment of wastewater containing EDTA-Cu(II) using the combined process of interior microelectrolysis and Fenton oxidation-Coagulation / Separation and Purification Technology 89:117~124
I. Kabdashi / 2009 / Complexing agent and heavy metal removals from metal plating effluent by electrocoagulation with stainless steel electrodes / Journal of Hazardous Materials 165:838~845
Fenglian Fu / 2009 / Fenton and Fenton-like reaction followed by hydroxide precipitation in the removal of Ni(II)from NiEDTA wastewater : A comparative study / Chemical Engineering Journal 155:769~774
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