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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 발행연도
- 2017.1
- 수록면
- 71 - 80 (10page)
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The chemical kinetics of steam reforming of polystyrene (PS) and polypropylene (PP) pyrolysis oil were studied usinga ruthenium-based catalyst. The experiments were performed in a tubular flow reactor at temperatures of 530-680oC,Weight Hourly Space Velocities (WHSVs) of 0.453-7.916 h−1, and different steam and pyrolysis oil gas-phaseconcentrations. The activation energy of steam reforming of polypropylene oil and polystyrene oil is 136 and 142 kJ/mol,respectively. The reaction orders of polypropylene and polystyrene oils were 0.42 and 0.37, respectively. Conversions ofpolypropylene and polystyrene oils were 2.0-50.3 and 1.9-45.3%, respectively. Indeed, a Langmuir-Hinshelwood (LH)mechanism requiring the dissociative adsorption of pyrolysis oil and steam at two different sites on plastics appeared tobe the most plausible pathway for the steam reforming reaction.
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참고문헌 (16)
참고문헌 신청
NIST / NIST standard reference database number 69, NTIS chemistry webbook
Plastic Waste Management Institute / Plastic products, Plastic waste and resource recovery
Williams, E. A. / 1997 / The pyrolysis of individual plastics and plastic mixture in a fixed bed reactor / Journal of Chemical Technology and Biotechnology 70(1):9~20
EPA / Waste materials-Density data
Kishimoto, H. / 2005 / Feasibility of n-dodecane fuel for solid oxide fuel cell with Ni- ScSZ anode / Journal of The Electrochemical Society 152(3):A532~A538
Plastic Waste Management Institute / Plastic products, Plastic waste and resource recovery
Williams, E. A. / 1997 / The pyrolysis of individual plastics and plastic mixture in a fixed bed reactor / Journal of Chemical Technology and Biotechnology 70(1):9~20
EPA / Waste materials-Density data
Kishimoto, H. / 2005 / Feasibility of n-dodecane fuel for solid oxide fuel cell with Ni- ScSZ anode / Journal of The Electrochemical Society 152(3):A532~A538
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