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The novel crosslinked anion exchange membrane with a high ion exchange capacityand stability was fabricated through a room temperature and solid-state radiation processing. Theanion-exchange membrane was prepared by solution casting method at the different compositionsof poly(diallyldimethylammonium chloride) and PVA substituted with methacryloyl group,and subsequently irradiated by electron beam to form 3D-network structure. From the variousanalytical results, the 3D-network crosslinked anion-exchange membrane exhibited not only ahigh ion exchange capacity (>1.7 meq·g-1) but a superior water stability (water uptake ≤ 30%)through a room temperature and quick radiation crosslinking process. Also, the prepared anionexchange membrane had better thermal stability compared to non crosslinked anion exchangemembrane (control).
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참고문헌 (18)
참고문헌 신청
Bhattacharya A / 2000 / Radiation and industrial polymers / Prog. Polym. Sci 25:371~401
Choi J-H / 2013 / Preparation and charaterization of crosslinked poly(butylene adipate-co-terephthalate)/polyhedral oligomeric silsesquioxane nanocomposite by electron beam irradiation / Radiat. Phys. Chem 82:100~105
Clough RL / 2001 / High-energy radiation and polymers : A review of commercial processes and emerging application / Nucl. Instrum. Methods Phys. Res. Sect. B 185:8~33
Hwang I-T / 2010 / Electron beam-induced crosslinking of poly(butylene adipate-co-terephthalate) / Nucl. Instrum. Methods Phys. Res., Sect. B 268:3386~3389
Kariduraganavar MY / 2006 / Ion-exchange membranes : preparative methods for electrodialysis and fuel cell applications / Desalination 197:225~246
Choi J-H / 2013 / Preparation and charaterization of crosslinked poly(butylene adipate-co-terephthalate)/polyhedral oligomeric silsesquioxane nanocomposite by electron beam irradiation / Radiat. Phys. Chem 82:100~105
Clough RL / 2001 / High-energy radiation and polymers : A review of commercial processes and emerging application / Nucl. Instrum. Methods Phys. Res. Sect. B 185:8~33
Hwang I-T / 2010 / Electron beam-induced crosslinking of poly(butylene adipate-co-terephthalate) / Nucl. Instrum. Methods Phys. Res., Sect. B 268:3386~3389
Kariduraganavar MY / 2006 / Ion-exchange membranes : preparative methods for electrodialysis and fuel cell applications / Desalination 197:225~246
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