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자료유형
학술저널
저자정보
Han-Sol Yun (Inha University) So-Young Shin (Inha University) Kwon-Jin Park (DGIST) Chun-Yeol You (DGIST) Nam-Hee Cho (Inha University)
저널정보
대한금속·재료학회 Electronic Materials Letters Electronic Materials Letters Vol.17 No.3
발행연도
2021.1
수록면
240 - 249 (10page)

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초록· 키워드

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Herein, the eff ect of microwave irradiation on the formation of γ-Fe 2 O 3 phase was investigated. The structural and chemicalfeatures of the γ-Fe 2 O 3 synthesized via microwave-assisted heat treatment (MWH) were examined in terms of precursors. Three diff erent types of precursors, i.e., FeC 2 O 4 ∙2H 2 O (FH), FeOOH, and Fe 3 O 4 , were used, and each precursor was heatedin a temperature range of 100–300 °C via MWH. Nanocrystalline γ-Fe 2 O 3 powders with a crystallite size of ~ 19 nm weresynthesized when the source FH was heat-treated at 120 °C for 20 min by MWH. The activation energy required for the formationof γ-Fe 2 O 3 powders was 21.4 kJ/mol, which is approximately one-third or one-quarter of the activation energy (68.5and 87.9 kJ/mol) reported for the synthesis of γ-Fe 2 O 3 via conventional heating. The lattice parameter of the synthesizedγ-Fe 2 O 3 phase expanded to 8.360 Å at 120 °C, whereas it contracted to 8.351 Å at 200 °C. This variation can be attributed tothe content of the surface-absorbed OH group. The values of the saturated magnetization and coercive force of the powdersincreased by approximately threefold with increasing crystallinity.

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