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논문 기본 정보

자료유형
학술저널
저자정보
Robert Bail (Dankook University) Joon Won Kang (Dankook University) You Jung Kang (Dankook University) Byung Doo Chin (Dankook University)
저널정보
대한금속·재료학회 Electronic Materials Letters Electronic Materials Letters Vol.17 No.1
발행연도
2021.1
수록면
74 - 86 (13page)

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초록· 키워드

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Solution processing of crosslinkable small molecular thin films is potentially attractive for the fabrication of large-area displaypanels based on organic light-emitting diodes (OLEDs). The characteristics of a wet-processed film made of a thermallycrosslinked small-molecular material can be controlled by simply adding a cosolvent to its solution. The surface morphologyof a nanometer-scale thin film made of N4,N4′-di(naphthalen-1-yl)-N4,N4′-bis(4-vinylphenyl)biphenyl-4,4′-diamine(VNPB), dissolved in chlorobenzene, improved dramatically after the addition of 20% cyclohexanone. At the same time,better resistance of the crosslinked layer to a number of solvents frequently used in the fabrication of the adjacent emittinglayer was achieved. Moreover, the maximum current efficiency in the binary solvent device increased significantly to 22.2Cd/A, compared to 9.7 Cd/A in the reference device without VNPB, and the device lifetime was extended by up to 74.8%. This illustrates a simple and additive-free strategy to prevent the formation of defects in solution processed thin-film stacksmade of small-molecular materials. The insights gained will be helpful in the solution-based manufacture of large-areaOLEDs and other optoelectronic components.

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