Effect of Concentrations of Fe2+ and Fe3+ on the Corrosion Behavior of Carbon Steel in Cl− and SO42− Aqueous Environments

Kui Xiao; Zhaoliang Li; Jialiang Song; Ziheng Bai; Wei Xue; Junsheng Wu; Chaofang Dong

추천

검색

자료유형: 학술저널

저자정보: Kui Xiao (University of Science and Technology Beijing) Zhaoliang Li (University of Science and Technology Beijing) Jialiang Song (University of Science and Technology Beijing) Ziheng Bai (University of Science and Technology Beijing) Wei Xue (University of Science and Technology Beijing) Junsheng Wu (University of Science and Technology Beijing) Chaofang Dong (University of Science and Technology Beijing)

저널정보: 대한금속·재료학회 Metals and Materials International Metals and Materials International Vol.27 No.8

발행연도: 2021.1

수록면: 2,623 - 2,633 (11page)

이용수

📌

연구주제

📖

연구배경

🔬

연구방법

🏆

연구결과

초록· 키워드

오류제보하기

The concentration of metal ions in aqueous environments signifcantly afects the formation of corrosion products and furthermetal corrosion. In this paper, the electrochemical behavior of carbon steel in the presence of Fe2+ or Fe3+ concentrationin Cl− and SO42− aqueous environments have been investigated using conventional electrochemical methods such as linearpolarization and alternating current impedance spectroscopy. The morphology and composition of carbon steel corrosionproducts were studied using scanning electron microscopy and laser Raman spectroscopy. The efects of corrosion productsand iron ions concentration on the corrosion of carbon steel were discussed. Corrosion products of carbon steel in aqueousenvironments were γ-FeOOH, γ-Fe2O3 and a small amount of α-Fe2O3. The addition of Fe2+ afected the cathode reactionof the electrode reaction, and promotes the formation of γ-FeOOH and Fe3O4. And with the increase of Fe2+ concentrationin the solution, the anode process of electrode reaction was suppressed. The addition of Fe3+ promoted the formation ofγ-Fe2O3 and Fe3O4. Fe3+ afected the ionization of water, causing the pH of the solution to drop. Fe3+ undergoes a redoxreaction with the matrix. Addition of Fe3+ ions promoted the formation of FeOOH, an intermediate product, which reactswith the anode product Fe2+. These factors all accelerated the corrosion process.

#Corrosion · Ferric ion · Carbon steel · Electrochemical · Aqueous environments

참고문헌 (0)

참고문헌 신청

참고문헌이 DBpia에서 서비스 중이라면, [참고문헌 신청]을 통해 등록해보세요

함께 읽어보면 좋을 논문

논문 유사도에 따라 DBpia 가 추천하는 논문입니다. 함께 보면 좋을 연관 논문을 확인해보세요!