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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 발행연도
- 2021.8
- 수록면
- 145 - 154 (10page)
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초록· 키워드
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This study investigates the effectiveness of a base heterogenous catalyst derived from waste Carica papaya peels in the transesterification of used vegetable oil (UVO). The calcined Carica papaya peels (CCPP) were characterised using scanning electron microscope-energy dispersive X-ray (SEM-EDX), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). The EDX result indicated that the ash contains various minerals with potassium (K) as the main active element in remove for the charge of the high catalytic activity. Response surface methodology (RSM) based on the Box Behnken design (BBD) was used to optimise and investigate the effect of the critical process parameters which include: the reaction time (50 – 70 min), catalyst loading (2.5 – 4.5 wt%) and methanol-to-oil molar ratio (9:1 – 15:1). The optimal reaction condition for the transesterification process was found to be catalyst loading of 3.5 wt%, methanol/oil molar ratio of 12:1, process reaction time of 60 min at constant reaction temperature of 65 ℃ which resulted in the maximum biodiesel yield of 97.5 wt%. The quality of the produced biodiesel was in agreement with ASTM standards. The catalyst was reused up to three times with minimal decrease in the catalytic activity in the biodiesel conversion. The study demonstrates the potential of waste biomass feedstocks in the production of sustainable biodiesel fuel.
목차
ABSTRACT
1. Introduction
2. Experimental
3. Result and Discussion
4. Conclusions
References
참고문헌 (40)
참고문헌 신청
Sahar, Sadaf S, Iqbal J, et al. Biodiesel production from waste cooking oil: An efficient technique to convert waste into biodiesel. Sustain. Cities Soc. 2018;41:220-226.
Balajii M, Niju S. A novel biobased heterogeneous catalyst derived from Musa acuminata peduncle for biodiesel production – Process optimization using central composite design. Energy Convers. Manag. 2019;189:118-131.
Etim AO, Musonge P, Eloka-Eboka AC. Effectiveness of biogenic waste-derived heterogeneous catalysts and feedstock hybridization techniques in biodiesel production. Biofuels Bioprod. Biorefin. 2020;14:620-649.
Betiku E, Okeleye AA, Ishola NB, Osunleke AS, Ojumu TV. Development of a novel mesoporous biocatalyst derived from kola nut pod husk for conversion of kariya seed oil to methyl esters: A case of synthesis, modeling and optimization studies. Catal. Letters. 2019;149:1772-1787.
Martial-Didier AK, Hubert KK, Jean PKE, Kablan T. Phytochemical properties and proximate composition of papaya (Carica papaya L. var solo 8) peels. Turkish J. Agric. - Food Sci. Technol. 2017;5:676-680.
Balajii M, Niju S. A novel biobased heterogeneous catalyst derived from Musa acuminata peduncle for biodiesel production – Process optimization using central composite design. Energy Convers. Manag. 2019;189:118-131.
Etim AO, Musonge P, Eloka-Eboka AC. Effectiveness of biogenic waste-derived heterogeneous catalysts and feedstock hybridization techniques in biodiesel production. Biofuels Bioprod. Biorefin. 2020;14:620-649.
Betiku E, Okeleye AA, Ishola NB, Osunleke AS, Ojumu TV. Development of a novel mesoporous biocatalyst derived from kola nut pod husk for conversion of kariya seed oil to methyl esters: A case of synthesis, modeling and optimization studies. Catal. Letters. 2019;149:1772-1787.
Martial-Didier AK, Hubert KK, Jean PKE, Kablan T. Phytochemical properties and proximate composition of papaya (Carica papaya L. var solo 8) peels. Turkish J. Agric. - Food Sci. Technol. 2017;5:676-680.
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