Development of Micro-Tubular Perovskite Cathode Catalyst with Bi-Functionality on ORR/OER for Metal-Air Battery Applications

Jeon, Yukwon; Kwon, Ohchan; Ji, Yunseong; Jeon, Ok Sung; Lee, Chanmin; Shul, Yong-Gun

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자료유형: 학술저널

저자정보: Jeon, Yukwon (School of chemistry, University of St Andrews) Kwon, Ohchan (Department of Chemical and Biomolecular Engineering, Yonsei University) Ji, Yunseong (Department of Chemical and Biomolecular Engineering, Yonsei University) Jeon, Ok Sung (Department of Chemical and Biomolecular Engineering, Yonsei University) Lee, Chanmin (Research Institute of Sustainable Manufacturing System, Intelligent Sustainable Materials R&D Group, Korea Institute of Industrial Technology [KITECH]) Shul, Yong-Gun (Department of Chemical and Biomolecular Engineering, Yonsei University)

저널정보: 한국화학공학회 화학공학 화학공학 제57권 제3호

발행연도: 2019.1

수록면: 425 - 431 (7page)

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As rechargeable metal-air batteries will be ideal energy storage devices in the future, an active cathode electrocatalyst is required with bi-functionality on both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) during discharge and charge, respectively. Here, a class of perovskite cathode catalyst with a micro-tubular structure has been developed by controlling bi-functionality from different Ru and Ni dopant ratios. A micro-tubular structure is achieved by the activated carbon fiber (ACF) templating method, which provides uniform size and shape. At the perovskite formula of $LaCrO_3$, the dual dopant system is successfully synthesized with a perfect incorporation into the single perovskite structure. The chemical oxidation states for each Ni and Ru also confirm the partial substitution to B-site of Cr without any changes in the major perovskite structure. From the electrochemical measurements, the micro-tubular feature reveals much more efficient catalytic activity on ORR and OER, comparing to the grain catalyst with same perovskite composition. By changing the Ru and Ni ratio, the $LaCr_{0.8}Ru_{0.1}Ni_{0.1}O_3$ micro-tubular catalyst exhibits great bi-functionality, especially on ORR, with low metal loading, which is comparable to the commercial catalyst of Pt and Ir. This advanced catalytic property on the micro-tubular structure and Ru/Ni synergy effect at the perovskite material may provide a new direction for the next-generation cathode catalyst in metal-air battery system.

#Metal-air battery #Cathode catalyst #Perovskite #Micro-tubular #Bi-functionality

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