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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한국광과학회 Photochemical & photobiological sciences : an international journal Photochemical & photobiological sciences : an international journal 제8권 제11호
- 발행연도
- 2009.1
- 수록면
- 1,603 - 1,610 (8page)
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초록· 키워드
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The effect of temperature on spectroscopic properties (stationary and time-resolved) of selected compounds belonging to the salicylideneaniline and hydroquinone families of photochromic Schiff bases is studied. The nonradiative decay of the excited keto tautomer consists of two components: the temperature-independent one (internal conversion, dominant below 200 K) and the temperaturedependent one (assigned to structural changes). The parameters of these components are remarkably different in the two families of the photochromic compounds. The influence of the hydrogen bonding ability of the solvent on the tautomeric equilibrium between the enol and keto forms indicates changes in the order of the ground state energy levels when going from methanol to trifluoroethanol.
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