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Phthalocyanine (Pc), which has an electron-rich, aromatic structure, exhibits excellent optical properties as well as thermal and chemical stability. Numerous Pc derivatives, based on highly conjugated ring systems, have been proposed to facilitate efficient energy or electron transfer. They have been frequently adopted for suitable applications such as sensors and photosensitizers. In this study, we present the synthesis and properties of various asymmetrical zinc-phthalocyanine (ZnPc) derivatives having a siloxane end-group linked with alkyl chain spacers of different lengths. A ZnPc-immobilized ITO electrode was prepared by the direct attachment of the siloxane anchoring group to the oxide surface. The synthesized Pcs and the immobilized Pc surfaces were fully characterized by various techniques. The effect of the alkyl spacer length on the optical and electrochemical properties of the Pc-functionalized electrode is briefly discussed.
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참고문헌 (26)
참고문헌 신청
X. Zhang / 2014 / Novel Donor [pi]- acceptor Conjugates-functionalized Zinc Phthalocyanines Application in Dye-sensitized Solar Cells / Asian J. Chem. 26:2229~2234
K. Sakamoto / 2009 / Syntheses and Functional Properties of Phthalocyanines / Materials 2:1127~1179
H. Wang / 2015 / Well-dispersed Cobalt Phthalocyanine Nanorods on Graphene for The Electrochemical Detection of Hydrogen Peroxide and Glucose Sensing / Sensor. Actuat. B-Chem. 216:298~306
V. Mani / 2016 / Electropolymerization of Cobalt Tetraamino-phthalocyanine at Reduced Graphene Oxide for Electrochemical Determination of Cysteine and Hydrazine / RSC Adv. 6:38463~38469
F. Arduini / 2013 / Acetylcholinesterase Biosensor Based on Self- assembled Monolayer-modified Gold-screen Printed Electrodes for Organophosphorus Insecticide Detection / Sensor. Actuat. B-Chem. 179:201~208
K. Sakamoto / 2009 / Syntheses and Functional Properties of Phthalocyanines / Materials 2:1127~1179
H. Wang / 2015 / Well-dispersed Cobalt Phthalocyanine Nanorods on Graphene for The Electrochemical Detection of Hydrogen Peroxide and Glucose Sensing / Sensor. Actuat. B-Chem. 216:298~306
V. Mani / 2016 / Electropolymerization of Cobalt Tetraamino-phthalocyanine at Reduced Graphene Oxide for Electrochemical Determination of Cysteine and Hydrazine / RSC Adv. 6:38463~38469
F. Arduini / 2013 / Acetylcholinesterase Biosensor Based on Self- assembled Monolayer-modified Gold-screen Printed Electrodes for Organophosphorus Insecticide Detection / Sensor. Actuat. B-Chem. 179:201~208
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