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논문 기본 정보

자료유형
학술저널
저자정보
정찬일 (중앙대학교 사회기반시스템공학부) 손주영 (중앙대학교 사회기반시스템공학부) 윤여민 (Univ of South Carolina Department of Civil and Environmental Engineering) 오재일 (Univ of South Carolina Department of Civil and Environmental Engineering)
저널정보
대한상하수도학회 상하수도학회지 상하수도학회지 제28권 제2호
발행연도
2014.1
수록면
235 - 248 (14page)

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초록· 키워드

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The widespread occurrence of dissolved endocrine disrupting compounds(EDCs) and pharmaceutical active compounds(PhACs) in water sources is of concern due to their adverse effects. To remove these chemicals, adsorption of EDCs/PhACs on granular activated carbon(GAC) was investigated, and bisphenol A, carbamazepine, diclofenac, ibuprofen, and sulfamethoxazole were selected as commonly occurring EDCs/PhACs in the aquatic environment. Various adsorption isotherms were applied to evaluate compatability with each adsorption in the condition of single-solute. Removal difference between individual and competitive adsorption were investigated from the physicochemical properties of each adsorbate. Hydrophobicity interaction was the main adsorption mechanism in the single-solute adsorption with order of maximum adsorption capacity as bisphenol A > carbamazepine > sulfamethoxazole > diclofenac > ibuprofen, while both hydrophobicity and molecular size play significant roles in competitive adsorption. Adsorption kinetic was also controled by hydrophobicity of each adsorbate resulting in higher hydrophobicity allowed faster adsorption on available adsorption site on GAC. EDCs/PhACs adsorption on GAC was determined as an endothermic reaction resulting in better adsorption at higher temperature ($40^{\circ}C$) than lower temperature ($10^{\circ}C$).

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