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논문 기본 정보

자료유형
학술저널
저자정보
정성명 (한밭대학교, 환경공학과) 남성영 (한국지질자원연구원 광물자원연구본부) 엄남일 (국립환경과학원, 환경자원연구부) 서주범 (한국지질자원연구원 광물자원연구본부) 유광석 (한국지질자원연구원 광물자원연구본부) 엄태인 (한밭대학교, 환경공학과) 안지환 (한국지질자원연구원 광물자원연구본부)
저널정보
한국광물학회 광물과 산업 광물과 산업 제26권
발행연도
2013.1
수록면
1 - 12 (12page)

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초록· 키워드

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In this study, an accelerated carbonation process was applied to stabilize hazardous heavy metals of industrial solid waste incineration (ISWI) bottom ash and fly ash, and to reduce $CO_2$ emissions. The most commonly used method to stabilize heavy metals is accelerated carbonation using a high water-to-solid ratio including oxidation and carbonation reactions as well as neutralization of the pH, dissolution, and precipitation and sorption. This process has been recognized as having a significant effect on the leaching of heavy metals in alkaline materials such as ISWI ash. The accelerated carbonation process with $CO_2$ absorption was investigated to confirm the leaching behavior of heavy metals contained in ISWI ash including fly and bottom ash. Only the temperature of the chamber at atmospheric pressure was varied and the $CO_2$ concentration was kept constant at 99% while the water-to-solid ratio (L/S) was set at 0.3 and $3.0dm^3/kg$. In the result, the concentration of leached heavy metals and pH value decreased with increasing carbonation reaction time whereas the bottom ash showed no effect. The mechanism of heavy metal-stabilization is supported by two findings during the carbonation reaction. First, the carbonation reaction is sufficient to decrease the pH and to form an insoluble heavy metal-material that contributes to a reduction of the leaching. Second, the adsorbent compound in the bottom ash controls the leaching of heavy metals; the calcite formed by the carbonation reaction has high affinity of heavy metals. In addition, approximately 5 kg/ton and 27 kg/ton $CO_2$ were sequestrated in ISWI bottom ash and fly ash after the carbonation reaction, respectively.

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