지원사업
학술연구/단체지원/교육 등 연구자 활동을 지속하도록 DBpia가 지원하고 있어요.
커뮤니티
연구자들이 자신의 연구와 전문성을 널리 알리고, 새로운 협력의 기회를 만들 수 있는 네트워킹 공간이에요.
이용수
초록· 키워드
오류제보하기
In this study, catalyst was made through incipient wetness method using palladium (Pd) as noble metal, indium (In) as secondary metal, and montmorillonite (MK10) and Al pillared montmorillonite (Al-MK10) as supporters. The nitrate reduction rate of the catalysts was measured by batch experiments where H2 gas was used as reducing agent and formic acid as pH controller. Transmission electron microscopy (TEM) equipped with energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) were all used to determine the elemental distribution of Pd, In, Al, and Si on catalysts. It was observed that Al pillaring increased the Al/Si elemental composition ratio and point of zero charge of MK10, but decreased its BET specific surface area and pore volume. The nitrate reduction rate of Al-MK10 Pd/In was 2.0 ~ 2.5 times higher than that of MK10 Pd/In using artificial groundwater (GW) in ambient temperature and pressure. Nitrate reduction rates in GW were 1.2 ~ 1.7 times lower than those in distilled deionized water (DDW). Nitrate reduction rates in acidic conditions were higher than those in neutral condition in both GW and DDW. The amount of produced NH3-N over degraded NO3- at acid conditions was lower than that of neutral condition. Even though the leaching of Pd after reaction was measured in DDW it was not detected when both Al-MK10 Pd/In and MK10 Pd/In were used in GW. The modification of montmorillonite as a supporter significantly increased the reductive catalytic activities of nitrates. However, the ratio of producing ammonia by-products to degraded nitrates in ambient temperature and pressure was similar.
목차
등록된 정보가 없습니다.
참고문헌 (29)
참고문헌 신청
Bhatnagar, A. / 2011 / A review of emerging adsorbents for nitrate removal from water / Chemical Engineering Journal 168(2):493~504
Chaplin, B. / 2012 / Critical review of Pd-based catalytic treatment of priority contaminants in water / Environmental Science & Technology 46(7):3655~3670
Dankova, Z. / 2014 / Influence of ultrasound irradiation on cadmium cations adsorption by montmorillonite / Desalination and Water Treatment 52:5462~5469
Gao, Z. / 2015 / Highly active Pd-In/mesoporous alumina catalyst for nitrate reduction / Journal of Hazardous Materials 286:425~431
Garron, A. / 2005 / Use of formic acid as reducing agent for application in catalytic reduction of nitrate in water / Water Research 39(13):3073~3081
Chaplin, B. / 2012 / Critical review of Pd-based catalytic treatment of priority contaminants in water / Environmental Science & Technology 46(7):3655~3670
Dankova, Z. / 2014 / Influence of ultrasound irradiation on cadmium cations adsorption by montmorillonite / Desalination and Water Treatment 52:5462~5469
Gao, Z. / 2015 / Highly active Pd-In/mesoporous alumina catalyst for nitrate reduction / Journal of Hazardous Materials 286:425~431
Garron, A. / 2005 / Use of formic acid as reducing agent for application in catalytic reduction of nitrate in water / Water Research 39(13):3073~3081
함께 읽어보면 좋을 논문
논문 유사도에 따라 DBpia 가 추천하는 논문입니다. 함께 보면 좋을 연관 논문을 확인해보세요!
-
Reduction of nitrate in groundwater by hematite supported bimetallic catalyst
Advances in environmental research
2016 .01
-
실험실 규모 칼럼에서의 팔라디움-인디움-알루미나 촉매를 이용한 지하수 내 질산성질소 제거
한국수처리학회지
2018 .01
-
PD에게 5G란 무엇인가?
방송과 미디어
2019 .07
-
Nitrate reduction by iron supported bimetallic catalyst in low and high nitrogen regimes
Advances in environmental research
2015 .01
-
Recovery of Palladium from the Spent Pd/Al₂O₃ catalyst by Leaching in Sulfuric Acid
한국에너지학회 학술발표회
2018 .04
-
Mg-4Al-2Sn 합금의 고온 기계적 특성에 미치는 Pd첨가의 영향
한국주조공학회지 (주조)
2017 .01
-
염산 침출용액을 이용한 Pd/Al₂O₃ 촉매에서 고순도 팔라듐 회수
청정기술
2020 .12
-
폐촉매로부터 Pd회수 및 이를 이용한 Pd/C 촉매 재제조 기술 개발
공업화학
2018 .01
-
산소환원반응용 PdxMyAuz/C@Pd 촉매의 합성 및 특성 분석
한국에너지학회 학술발표회
2016 .04
-
Real-time analysis of electrochemical nitrate-to-nitrogen conversion on Copper-Palladium alloy
대한환경공학회 학술발표논문집
2020 .11
-
Biomass and lipid production from three microalgae using two phase culture process with stresses of nitrate concentration
한국생물공학회 학술대회
2019 .04
-
Amorphous Co3O4-Decorated Pd as an Efficient Electrocatalyst for Methanol Oxidation
NANO
2017 .01
-
근골격 해부학에 근거한 텐던 매커니즘 기반 다자유도 로봇 핸드(SSP Mk.1, SSP Mk.2)의 기구학적 설계 및 분석
제어로봇시스템학회 국내학술대회 논문집
2021 .06
-
Pd 나노 촉매가 도입된 나피온 막의 기계적 강도 및 고분자 전해질막 연료전지 (PEMFC) 성능
한국수소및신에너지학회논문집
2016 .06
-
연료전지 전극촉매용 팔라듐 나노입자 형상 제어 및 산소환원반응 성능 평가
한국수소및신에너지학회논문집
2018 .10
-
Comparing various factors affecting pathway on the reduction of nitrate with zero valent iron
대한환경공학회 학술발표논문집
2015 .10
-
Metal nitrate complexes as Post PEO conversion coating agents for corrosion protection of Al-Mg alloys
한국표면공학회 학술발표회 초록집
2019 .05
-
금속-세라믹 코어-쉘 복합체에 담지된 Ni 금속 촉매를 적용한 CO₂ 메탄화 반응 특성연구
청정기술
2022 .06
-
무전해도금을 위한 Pd촉매액의 특성 비교
한국표면공학회 학술발표회 초록집
2017 .11
이 논문의 저자 정보
최근 본 자료
댓글(0)
0