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Graphene/poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP) composite films were prepared by the solution casting method. The resultant 2 wt% graphene/ PVDF-HFP composite films were uniaxially drawn at $50^{\circ}C$, $75^{\circ}C$, and $100^{\circ}C$. Investigation of the surface morphology of these films confirmed that the orientation of the polymer matrix. The XRD results showed ${\alpha}$-phase crystals. With increasing drawing temperature, the (002) reflections of graphene decreased and the (100) and (020) planes of the ${\alpha}$-phase of PVDF-HFP increased. DSC thermograms indicated no change in the melting temperature but a slight increase in crystallinity with increasing drawing temperatures. The surface resistivity of the graphene/PVDF-HFP composite films in the case of $75^{\circ}C$ drawing temperature were slightly lower than those in the case of the other two temperatures.
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참고문헌 (19)
참고문헌 신청
S. H. Lee / 2011 / Tailored Assembly of Graphene from Solvent Dispersion / Polym. Sci. Tech 22:130~136
J. Molina / 2016 / Graphene-based Fabrics and Their Applications : A Review / RSC Adv 6:68261~68291
X. Ji / 2016 / Review of Functionalization, Structure and Properties of Graphene/polymer Composite Fibers / Composites: Part A 87:29~45
J. Xu / 2015 / Polypyrrole/reduced Graphene Oxide Coated Fabric Electrodes for Supercapacitor Application / Organic Electronics 24:153~159
C. Zhao / 2015 / Reduced Graphene Oxide and Polypyrrole/reduced Graphene Oxide Composite Coated Strechable Fabric Electrodes for Supercapacitor Application / Electrochinica Acta 172:12~19
J. Molina / 2016 / Graphene-based Fabrics and Their Applications : A Review / RSC Adv 6:68261~68291
X. Ji / 2016 / Review of Functionalization, Structure and Properties of Graphene/polymer Composite Fibers / Composites: Part A 87:29~45
J. Xu / 2015 / Polypyrrole/reduced Graphene Oxide Coated Fabric Electrodes for Supercapacitor Application / Organic Electronics 24:153~159
C. Zhao / 2015 / Reduced Graphene Oxide and Polypyrrole/reduced Graphene Oxide Composite Coated Strechable Fabric Electrodes for Supercapacitor Application / Electrochinica Acta 172:12~19
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