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자료유형
학술저널
저자정보
Sengupta, P. (Rubber Technology, Faculty of Chemical Technology, University of Twente) Sengers, W.G.F. (Polymer Materials and Engineering, Faculty of Applied Sciences, Delft University of Technology) Gotsis, A.D. (Polymer Materials and Engineering, Faculty of Applied Sciences, Delft University of Technology) Noordermeer, J.W.M. (Rubber Technology, Faculty of Chemical Technology, University of Twente)
저널정보
한국고무학회 Elastomers and composites 엘라스토머 및 콤포지트 제38권 제1호
발행연도
2003.1
수록면
27 - 37 (11page)

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This work presents a comparative study of the morphology and structure related properties of thermoplastic elastomer blends based on SEBS/PP/Oil and dynamically vulcanized EPDM/PP/Oil. A combination of ruthenium oxide staining and low voltage scanning electron microscopy (LVSEM) was found to be suitable for the study of morphology of these highly oil extended blends. h close analogy was found in the mechanical, thermal and rheological properties of the two systems made in an internal Brabender mixer and co-rotating turin screw extruder. The morphology of the blends, as made by the two techniques, was found to be significantly different. In the case of TPVs, the blonds made in the extruder had smaller EPDM domains and better tensile properties. In the case of SEBS, the blends made in the Brabender had more co-continuous phases and showed better tensile properties. Crystallization behavior of the isotactic polypropylene in the blends was found to be influenced by the type of rubber. Blends of SEBS/PP crystallized at a lower temperature than the TPVs. These differences were probably caused by differences in the nucleating ability of the two rubbers.

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