지원사업
학술연구/단체지원/교육 등 연구자 활동을 지속하도록 DBpia가 지원하고 있어요.
커뮤니티
연구자들이 자신의 연구와 전문성을 널리 알리고, 새로운 협력의 기회를 만들 수 있는 네트워킹 공간이에요.
초록· 키워드
오류제보하기
It is knwon that in the reaction of .alpha.-diethylaminoacetophenone with potassium cyanide and ammonium carbonate in dilute alcohol solution, 5-phenylhydantoin is formed. In this study the mechanism of the reaction by which diethylaminomethyl group is eliminated, was investigated with applying GC/MS-system. From the fragmentation pattern of mass spectrum of the unknwon compound, which has mol peak 112, it was identified as diethylaminoacetonitrile. According to our GC/MS study of the reaction mixture, it seems likely that diethylaminomethyl group is eliminated neither through the alkali degradation of .alpha.-diethylaminoacetophenone to aldehyde nor after the anticipated hydantoin formation. But it is believed that in the course of ring formation through an unidentified mechanism diethylaminomethyl group is eliminated.
목차
등록된 정보가 없습니다.
참고문헌 (0)
참고문헌 신청함께 읽어보면 좋을 논문
논문 유사도에 따라 DBpia 가 추천하는 논문입니다. 함께 보면 좋을 연관 논문을 확인해보세요!
-
히단토인 유도체 형성에 있어서 $\alpha$-Diethaylaminoacetophenone의 탈이반응
약학회지
1978 .01
-
$\alpha$-Piperidinoacetophenone의 Hydantoin 형성 반응
약학회지
1983 .01
-
New inhibitors of the NF-kB activation and NO production from Artemisia sylvatica
대한약학회 학술대회
2003 .01
-
Possible target for G protein antagonist: Identification of specific amino acid residue responsible for the molecular interaction of G$\alpha$ 16 with chemoattractant C5a receptor.
한국응용약물학회 춘계학술발표논문집
2000 .01
-
An Efficient Synthesis of Cyclic $\alpha$, $\alpha$-Disubstituted $\alpha$-Amino Acids
대한약학회 학술대회
2001 .01
-
Microbial $9{\alpha}$-Hydroxylase:Epoxidation of 9(11)-dehydro-$17{\alpha}$-methyl-testosterone
Archives of pharmacal research : a publication of the Pharmaceutical Society of Korea
1997 .01
-
Frontal Alpha Asymmetry Correlates with Suicidal Behavior in Major Depressive Disorder
Clinical Psychopharmacology and Neuroscience
2019 .01
-
적출한 흰쥐 대동맥에 있어서 postsynaptic $\alpha_1$-, $\alpha_2$- 아드레날린 수용체에 관한 연구
약학회지
1986 .01
-
<sup>211</sup>At and <sup>211</sup>At-labeled radiopharmaceuticals for targeted alpha therapy
대한방사성의약품학회지
2018 .01
-
T 세포 하이브리도마에 의한 ${\alpha}2-Macroglobulin$의 생산
약학회지
1994 .01
-
Potential drug targets in the GPCR-$G{\alpha}_{12}/G{\alpha}_{13}$ signaling pathways
한국응용약물학회 춘계학술발표논문집
2008 .01
-
Brain Alpha Rhythm Component in fMRI and EEG
의공학회지
2005 .01
-
$(\pm)-\alpha-Hydroxy-\alpha$-(p-Chlorobiphenyl)acetic acid 합성과 분할
약학회지
1995 .01
-
Stereoselective synthesis of novel 4′$\alpha$-C-methyl branched novel carbocyclic nucleosides
대한약학회 학술대회
2002 .01
-
FK506과 cyclosporin A가 기관지상피세포, 단핵구, 림프구 및 폐포대식세포에서 $I{\kappa}B{\alpha}$ 분해 및 $IKK{\alpha}$ 활성에 미치는 효과
Tuberculosis and Respiratory Diseases
2003 .01
-
팔방산호충류에서 분리한 해양 스테롤 화합물의 혈소판 응집 억제작용
약학회지
1997 .01
-
Synthesis of novel compounds for the inhibition of TNF-$\alpha$ production
대한약학회 학술대회
2000 .01
-
그늘쑥의 Sesquiterpene Lactone 성분
약학회지
2001 .01
-
5-Phenylhydantoin의 아미노메칠화 반응
약학회지
1982 .01
이 논문의 저자 정보
최근 본 자료
댓글(0)
0