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In this paper, the efficiency and the inhibition mechanisms of cobalt salts (cobalt nitrate and cobalt-exchangesilica Co/Si) for the corrosion protection of AA2024 were investigated in a neutral aqueous solution byusing the electrochemical impedance spectroscopy (EIS) and polarization curves. The experimental measurementssuggest that cobalt cation plays a role as a cathodic inhibitor. The efficiency of cobalt cation was importantat the concentration range from 0.001 to 0.01 M. The formation of precipitates of oxides/hydroxides ofcobalt on the surface at low inhibitor concentration was confirmed by the Scanning Electron Microscopy/EnergyDispersive X-Ray Spectroscopy (SEM/EDS) analysis. EIS measurements were also conducted for the AA2024surface covered by water-based epoxy coating comprising Co/Si salt. The results obtained from exposurein the electrolyte demonstrated the improvement of the barrier and inhibition properties of the coating exposedin the electrolyte solution for a lengthy time. The SEM/EDS analysis in artificial scribes of the coatingafter salt spray testing revealed the release of cobalt cations in the coating defect to induce the barrierlayer on the exposed AA2024 substrate.

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