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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한국고분자학회 폴리머 폴리머 제43권 제6호
- 발행연도
- 2019.11
- 수록면
- 807 - 815 (9page)
- DOI
- 10.7317/pk.2019.43.6.807
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초록· 키워드
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Dendronized exo-7-oxanorbornene monomers were synthesized and polymerized via thiol-Michael coupling and ring-opening metathesis polymerization. The polymerization rate was highly dependent on the steric hindrance of the terminal group. The space linker between the polymerizable group and dendron was a crucial factor. Ru-based kinetics was investigated using nuclear magnetic resonance (NMR), which showed that the monomer was completely converted to a generally narrow polydispersity material. The second generation of functional macromonomer was grafted from the first with a different linker length and consumed completely at 50℃ in toluene. Considering the properties of the space linker, we found that a short space linker of dendronized exo-7-oxanorbornene macromonomer leads to narrow molecular weight distributions of obtained dendronized polymers. This work provides a further understanding of the effect of steric hindrance on dendronized polymers, thereby allowing the development of functional materials.
목차
Abstract
Introduction
Experimental
Results and Discussion
Conclusions
References
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