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As langasite A3BC3D2O14 compounds with piezoelectric properties exhibit no phase transition up to the melting point of 1,400-1,500℃, many high temperature applications are expected for the SAW filter, temperature sensor, pressure sensor, and so on, based on the digital transformation of wider bandwidth and higher-bit rates. It has a larger electromechanical coupling factor compared to quartz and also nearly the same temperature stability as quartz. The La3Ga5SiO14 (LGS) crystal with the Ca3Ga2Ge4O14-type crystal structure was synthesized and the crystal structure was analyzed by Mill et al. It is also an important feature that the growth of the single crystal is easy. In the case of threeelement compounds such as [R3]A[Ga]B[Ga3]C[GaSi]DO14 (R=La, Pr and Nd), the piezoelectric constant increases with the ionic radius of R. In this study, crystal structures of four-element compounds such as [A3]A[B]B[Ga3]C [Si2]DO14 (A = Ca or Sr, B = Ta or Nb) are analyzed by a single crystal X-ray diffraction, and the mechanism and properties of the piezoelectricity depending on the species of cation was clarified based on the crystal structure.

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