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학술연구/단체지원/교육 등 연구자 활동을 지속하도록 DBpia가 지원하고 있어요.
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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 발행연도
- 2012.9
- 수록면
- 157 - 165 (9page)
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초록· 키워드
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This experimental study was performed to obtain thermal energy from the combustion of synthetic gas, produced by the pyrolysis of insulating oil containing polychlorinated biphenyls (PCBs) in a high temperature and high pressure reactor. The average synthetic gas generated was 59.67 Am3/hr via the steady state gasification of insulating oil waste (20 kg/hr) with average concentrations (standard deviation) of CO₂, CO, and H₂ in the synthetic gas of 38.63 ± 3.11%, 35.18 ± 1.93%, and 28.42 ± 1.68%, respectively. The concentrations of the PCBs in the transformer insulating oil and synthetic gas after its gasification, and the concentrations of the dioxins that could be produced from the incomplete degradation of PCBs were measured. It was revealed that the PCBs in the insulating oil were composed of the series from tetrachlorobiphenyl to octachlorobiphenyl. However, only the #49, #44, #52, and #47/75/48 congeners were detected from the synthetic gas after gasification of the insulating oil and in the flue gas from the combustor. In conclusion, the experimental conditions suggested in this study were very useful for the appropriate treatment of insulating oil containing PCBs. Also, fuel gas containing CO and H₂ can be obtained from the pyrolysis of insulating oil containing PCBs.
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참고문헌 (16)
참고문헌 신청
1. [인터넷자원] - US Environmental Protection Agency / / Polychlorinated biphenyls (PCBs) [Internet]
2. [학술지(정기간행물)] - Jensen S / 1969 / DDT and PCB in marine animals from Swedish waters / Nature 224 : 247 ~ 250
3. [학술지(정기간행물)] - Breivik K / 2002 / Towards a global historical emission inventory for selected PCB congeners: a mass balance approach. 1. Global production and consumption / Sci. Total Environ 290 : 181 ~ 198
4. [단행본] - United Nations Environment Programme (UNEP) Chemicals / 1999 / Guidelines for the identification of PCBs and materials containing PCBs / UNEP Chemicals
5. [학술지(정기간행물)] - Hawari J / 1992 / Sensitized photolysis of polychlorobiphenyls in alkaline 2-propanol: dechlorination of Aroclor 1254 in soil samples by solar radiation / Environ. Sci. Technol 26 : 2022 ~ 2027
2. [학술지(정기간행물)] - Jensen S / 1969 / DDT and PCB in marine animals from Swedish waters / Nature 224 : 247 ~ 250
3. [학술지(정기간행물)] - Breivik K / 2002 / Towards a global historical emission inventory for selected PCB congeners: a mass balance approach. 1. Global production and consumption / Sci. Total Environ 290 : 181 ~ 198
4. [단행본] - United Nations Environment Programme (UNEP) Chemicals / 1999 / Guidelines for the identification of PCBs and materials containing PCBs / UNEP Chemicals
5. [학술지(정기간행물)] - Hawari J / 1992 / Sensitized photolysis of polychlorobiphenyls in alkaline 2-propanol: dechlorination of Aroclor 1254 in soil samples by solar radiation / Environ. Sci. Technol 26 : 2022 ~ 2027
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UCI(KEPA) : I410-ECN-0101-2017-539-001538359