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자료유형
학술저널
저자정보
저널정보
대한환경공학회 Environmental Engineering Research Environmental Engineering Research 제13권 제4호
발행연도
2008.12
수록면
171 - 176 (6page)

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Studies on visible-light-driven photocatalysis of air pollutants at indoor air quality (IAQ) levels have been limited. Current study investigated visible-light derived photocatalysis with N-doped and S-doped titanium dioxide (TiO₂) for the control of benzene at indoor levels. Two preparation processes were employed for each of the two types of photocatalyst: urea-Degussa P-25 TiO₂ and titania-colloid methods for the N-doped TiO₂; and titanium isopropoxid- and tetraisopropoxide-thiourea methods for the S-doped TiO₂. Furthermore, two coating methods (EDTA- and acetylacetone- dissolving methods) were tested for both the N-doped and S-doped TiO₂. The two coating methods exhibited different photocatalytic degradation efficiency for the N-doped photocatalysts, whereas they did not exhibit any difference for the S-doped photocatalysts. In addition, the two doping processes showed different photocatalytic degradation efficiency for both the S-doped and N-doped photocatalysts. For both the N-doped and S- doped TiO₂, the photocatalytic oxidation (PCO) efficiency increased as the hydraulic diameter (HD) decreased. The degradation efficiency determined via a PCO system with visible-light induced TiO₂ was lower than that with UV-light induced unmodified TiO₂, which was obtained from previous studies. Nevertheless, it is noteworthy that for the photocatalytic annular reactor with the HD of 0.5 cm, PCO efficiency increased up to 52% for the N-doped TiO₂ and 60% for the S-doped TiO₂. Consequently, when combined with the advantage of visible light use over UV light use, it is suggested that with appropriate HD conditions, the visible-light-assisted photocatalytic systems can also become an important tool for improving IAQ.

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