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The anodization of ADC12 aluminum alloy was investigated in the metal anionic acid media. Anodic oxide films containing foreign elements were formed on ADC12 Al alloy by anodization in the anion complex solution. Furthermore, the rough surface and cracks were considerably smoothened by the deposit of metal anions. When the size of metal anion was small, relatively large amount of metal anions was loaded in anodic films. Existence of MoO₃, TiO₂ and MgO was confirmed by XPS. According to the results of Tafel analysis, Mo oxide represented the most noble anti-corrosion potential due to MoS2 formation. Corrosion current densities were generally higher than that of pristine anodic oxide without anion complexes.
목차
Abstract
1. Introduction
2. Experimental Details
3. Results and Discussion
4. Conclusions
References
참고문헌 (23)
참고문헌 신청
W. A. Badawy, F. M. Al-Kharafi, A. S. El-Azab, Electrochemical behavior and corrosion inhibition of al, al-6061 and al-cu in neutral aqueous solutions, Corros. Sci 41 (1999) 709-727.
V. Guillaumin, G. Mankowski, Localized corrosion of 2024 t351 aluminium alloy in chloride media, Corros. Sci. 41 (1999) 421-438.
C. Blanc, B. Lavelle, G. Mankowski, The role of precipitates enriched with copper on the susceptibility to pitting corrosion of the 2024 aluminium alloy, Corros. Sci. 39 (1997) 495-510.
H. Dodiuk, A. E. Yaniv, I. E. Klein, N. Fin, L. Drori, Chemical interaction in the system aluminum oxide-primer-adhesive, Appl. Surf. Sci. 25 (1986) 137-153.
J. Choi, J. K. Lee, J. H. Lim, S. J. Kim, Technology trends in fabrication of nanostructures of metal oxides by anodization and their applications, J. Korean Ind. Eng. Chem. 19 (2008) 249-258.
V. Guillaumin, G. Mankowski, Localized corrosion of 2024 t351 aluminium alloy in chloride media, Corros. Sci. 41 (1999) 421-438.
C. Blanc, B. Lavelle, G. Mankowski, The role of precipitates enriched with copper on the susceptibility to pitting corrosion of the 2024 aluminium alloy, Corros. Sci. 39 (1997) 495-510.
H. Dodiuk, A. E. Yaniv, I. E. Klein, N. Fin, L. Drori, Chemical interaction in the system aluminum oxide-primer-adhesive, Appl. Surf. Sci. 25 (1986) 137-153.
J. Choi, J. K. Lee, J. H. Lim, S. J. Kim, Technology trends in fabrication of nanostructures of metal oxides by anodization and their applications, J. Korean Ind. Eng. Chem. 19 (2008) 249-258.
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UCI(KEPA) : I410-ECN-0101-2016-581-002873293