지원사업
학술연구/단체지원/교육 등 연구자 활동을 지속하도록 DBpia가 지원하고 있어요.
커뮤니티
연구자들이 자신의 연구와 전문성을 널리 알리고, 새로운 협력의 기회를 만들 수 있는 네트워킹 공간이에요.
논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 발행연도
- 2014.4
- 수록면
- 36 - 49 (14page)
이용수
초록· 키워드
오류제보하기
The synthesis of di-methyl-carbonate (DMC) with urea and methanol occurred by two step reactions. In first step, methyl-carbamate (MC) is produced by the reaction between urea and methanol. In second step, DMC is synthesized by the catalytic reaction between MC and methanol over the catalyst. In this study, ZnO was used as the catalyst for the synthesis of DMC and the reaction behavior for the synthesis of DMC over ZnO catalysts, which have a different surface area, was investigated. The surface area of ZnO was controlled with the change of calcination temperature and that calcined at with 400℃ was 27㎡ /g. Meanwhile, the yield of products was investigated with the reactionconditions, such as the temperature, the pressure, the time, the amount of catalyst and the agitation speed. The yield of DMC was changed with changing reaction conditions. It was also concluded that the production of N-methyl-methyl-carbamate (N-MMC), which is the by-product produced by the reaction between MC and DMC, taken affected in the yield of DMC. The maximum yield of DMC was obtained to approximately 23.9% in the test under the suitable reaction conditions, which was performed with 1 gram of catalyst at 175℃, 25 bar and 600 rpm for 10 h. The yield of DMC increased with the increase of catalyst’s surface area, while the changing surface area of catalyst was exhibited the little effect for the production of N-MMC.
목차
Abstract
1. 서론
2. 실험
3. 결과 및 고찰
4. 결론
참고문헌
참고문헌 (17)
참고문헌 신청
Tundo, P. / 2002 / The Chemistry of Dimethyl Carbonate / Acc. Chem. Res 35:706
Sun, J. / 2005 / Synthesis of dimethyl carbonate from urea and methanol using polyphosphoric acid as catalyst / J. Mol. Catal. A: Chem 239:82
Delledonne, D. / 2001 / Developments in the production and application of dimethylcarbonate / Appl. Catal. A: Gen 221:241
김윤민 / 2011 / 고압반응 하에서 요소와 메탄올을 사용한 메틸카바메이트와 디메틸카보네이트 제조에 관한 금속산화물 촉매 및 이온성액체의 영향 / Korean Chemical Engineering Research(HWAHAK KONGHAK) 49(6):732~738
서은실 / 2002 / Methanol과 CO2로부터 디메틸카보네이트의 직접합성 / Korean Chemical Engineering Research(HWAHAK KONGHAK) 40(1):9~15
Sun, J. / 2005 / Synthesis of dimethyl carbonate from urea and methanol using polyphosphoric acid as catalyst / J. Mol. Catal. A: Chem 239:82
Delledonne, D. / 2001 / Developments in the production and application of dimethylcarbonate / Appl. Catal. A: Gen 221:241
김윤민 / 2011 / 고압반응 하에서 요소와 메탄올을 사용한 메틸카바메이트와 디메틸카보네이트 제조에 관한 금속산화물 촉매 및 이온성액체의 영향 / Korean Chemical Engineering Research(HWAHAK KONGHAK) 49(6):732~738
서은실 / 2002 / Methanol과 CO2로부터 디메틸카보네이트의 직접합성 / Korean Chemical Engineering Research(HWAHAK KONGHAK) 40(1):9~15
이 논문의 저자 정보
이 논문과 함께 이용한 논문
최근 본 자료
댓글(0)
0
UCI(KEPA) : I410-ECN-0101-2016-563-001133141