Alginate has been widely used in various tissue regenerations, and it has also recently been applied to bone tissue regeneration due to its ability to promote cell growth and bone tissue development. However, although alginate has excellent biocompatibility for the tissue regeneration, it suffers from low mechanical properties and low processability to obtain artificially controlled internal microstructures. In this study, to overcome the limitations, we propose a new cell-coating process supplemented with cells in alginate. The cell-coated PCL/alginate scaffold consisted of alginate with a mixture of cells coated on the PCL struts. The fabricated scaffold showed highly cellular behavior and uniform cell density.