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논문 기본 정보

자료유형
학술저널
저자정보
Suw Young Ly (Seoul National University of Science and Technology) Dae Hong Kim (Asia Pacific International School) Ga Eun Lee (Asia Pacific International School)
저널정보
한국독성학회 Toxicological Research Toxicological Research Vol.29 No.3
발행연도
2013.9
수록면
211 - 215 (5page)

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초록· 키워드

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The trace toxic metal copper was assayed using mercury immobilized on a carbon nanotube electrode (MCW), with a graphite counter and a reference electrode. In this study, a macro-scale convection motor was interfaced with a MCW three-electrode system, in which a handmade MCW was optimized using cyclic- and square-wave stripping voltammetry. An analytical electrolyte for tap water was used instead of an expensive acid or base ionic solution. Under these conditions, optimum parameters were 0.09 V amplitude, 40 Hz frequency, 0.01 V incremental potential, and a 60-s accumulation time. A diagnostic working curve was obtained from 50.0 to 350 μg/L. At a constant Cu(II) concentration of 10.0 μg/L, the statistical relative standard deviation was 1.78% (RSD, n = 15), the analytical accumulation time was only 60 s, and the analytical detection limit approached 4.6 μg/L (signal/noise = 3). The results were applied to nontreated drinking water. The content of the analyzed copper using 9.0 and 4.0 μg/L standards were 8.68 μg/L and 3.96 μg/L; statistical values R<SUP>2</SUP> = 0.9987 and R<SUP>2</SUP> = 0.9534, respectively. This method is applicable to biological diagnostics or food surveys.

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INTRODUCTION
MATERIALS AND METHODS
RESULTS AND DISCUSSION
REFERENCES

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