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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 발행연도
- 2013.3
- 수록면
- 25 - 29 (5page)
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초록· 키워드
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Poly ketone (PK) was photo-oxidized by UV/ozone irradiation and the effect of UV energy on the surface properties of the UV-irradiated PK film was investigated by the measurement of reflectance, surface roughness, contact angles, ESCA, and ATR. Reflectance, particularly at the wavelength of 380nm, decreased with increasing UV energy. And the irradiation produced nano-scale roughness on the surface uniformly. The maximum surface roughness increased from 25.3nm for the unirradiated sample to 104.9nm at the irradiation of 42.4J/cm². The improvement in hydrophilicity was caused by the introduction of polar groups such as C-O and C=O bonds resulting in higher O<sub>1s</sub>/C<sub>1s</sub>. The surface energy of PK film increased from 43.3 mJ/m² for the unirradiated sample to 71.9 mJ/m² at the irradiation of 31.8J/cm². The zeta potential of the UV-irradiated PK decreased with increased UV energy and the dyeability to cationic dyes increased accordingly, resulting from the photochemically introduced anionic and dipolar dyeing sites on the PK films surfaces.
목차
Abstract
1. 서론
2. 실험
3. 결과 및 고찰
4. 결론
참고문헌
참고문헌 (15)
참고문헌 신청
1. [학술지(정기간행물)] - A. Sen / 1993 / Mechanistic Aspects of Metal-Catalyzed Alternating Copolymerization of Olefins with Carbon Monoxide / Acc. Chem. Res 26 : 303 ~
2. [학술지(정기간행물)] - P. Gupta / 2001 / Development of High-strength Fibers from Aliphatic Polyketones by Melt Spinning and Drawing / Journal of Applied Polymer Science 82 (7) : 1794 ~
3. [학술지(정기간행물)] - O. Ohsawa / 2010 / Preparation and Characterization of Polyketone( PK) Fibrous Membrane via Electrospinning / Polymer 51 (9) : 2007 ~
4. [학술지(정기간행물)] - J. Guo / 2012 / Synthesis of Novel Bipyridyl Ligands and Application in Preparation of Polyketone / Journal of Applied Polymer Science 123 (6) : 3292 ~
5. [학술지(정기간행물)] - J. S. Won / 2012 / Interfacial Adhesion Properties of Oxygen Plasma Treated Polyketone Fiber with Natural Rubber / Journal of Adhesion and Interface 13 (1) : 45 ~
2. [학술지(정기간행물)] - P. Gupta / 2001 / Development of High-strength Fibers from Aliphatic Polyketones by Melt Spinning and Drawing / Journal of Applied Polymer Science 82 (7) : 1794 ~
3. [학술지(정기간행물)] - O. Ohsawa / 2010 / Preparation and Characterization of Polyketone( PK) Fibrous Membrane via Electrospinning / Polymer 51 (9) : 2007 ~
4. [학술지(정기간행물)] - J. Guo / 2012 / Synthesis of Novel Bipyridyl Ligands and Application in Preparation of Polyketone / Journal of Applied Polymer Science 123 (6) : 3292 ~
5. [학술지(정기간행물)] - J. S. Won / 2012 / Interfacial Adhesion Properties of Oxygen Plasma Treated Polyketone Fiber with Natural Rubber / Journal of Adhesion and Interface 13 (1) : 45 ~
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UCI(KEPA) : I410-ECN-0101-2014-570-003007223