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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 발행연도
- 2012.12
- 수록면
- 239 - 246 (8page)
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초록· 키워드
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The binding isotherms of ionic dyes with Poly(vinylpyrrolidone) in aqueous solution were determined by the dynamic dialysis technique. The shape of the isotherms of cationic dye, C. I. Basic Red 18 with poly(vinlypyrrolidone) showed a partition type. It suggests that the binding involves a non-cooperative mode. Isotherms of an anion dye, a synthesized dye by coupling of diazotized m-trifluoromethylaniline with 2-naphthol-6-sulfonic acid, were sigmoid type and showed multimode interaction. The results were interpreted by the McGhee von Hippel theory. The thermodynamic parameters for the complex formation of the dyes-polymer were calculated from their temperature dependences of the intrinsic binding constant.
목차
Abstract
1. Introduction
2. Experimental
3. Results and Discussion
4. Conclusions
Acknowledgement
References
참고문헌 (14)
참고문헌 신청
1. [학술지(정기간행물)] - B. F. Bradley / 1959 / Aggregation of Dyes Bound to Polyanions / PNAS 45 (7) : 944 ~
2. [학술지(정기간행물)] - G. Schwarz / 1968 / General Theoretical Approach to the Thermodynamic and Kinetic Properties of Cooperative Intramolecular Transformations of Linear / Biopolymers 6 (6) : 873 ~
3. [학술지(정기간행물)] - J. D. McGhee / 1974 / Theoretical Aspects of DNA-Protein Interactions: Cooperative and Non-cooperative Binding of Large Ligands to a One-dimensional Homogeneous lattice / J. Mol. Biol. 86 (2) : 469 ~
4. [학술지(정기간행물)] - J. L. Bresloff / 1975 / DNA-ethidium Reaction Kinetics: Demonstration of Direct Ligand Transfer between DNA Binding Sites / J. Mol. Biol. 95 (1) : 103 ~
5. [학술지(정기간행물)] - B. Ramanathan / 1978 / A Quantitative Analysis of Excluded-site Effects for Highly Cooperative Binding Systems / Biopolymers 17 (9) : 2171 ~
2. [학술지(정기간행물)] - G. Schwarz / 1968 / General Theoretical Approach to the Thermodynamic and Kinetic Properties of Cooperative Intramolecular Transformations of Linear / Biopolymers 6 (6) : 873 ~
3. [학술지(정기간행물)] - J. D. McGhee / 1974 / Theoretical Aspects of DNA-Protein Interactions: Cooperative and Non-cooperative Binding of Large Ligands to a One-dimensional Homogeneous lattice / J. Mol. Biol. 86 (2) : 469 ~
4. [학술지(정기간행물)] - J. L. Bresloff / 1975 / DNA-ethidium Reaction Kinetics: Demonstration of Direct Ligand Transfer between DNA Binding Sites / J. Mol. Biol. 95 (1) : 103 ~
5. [학술지(정기간행물)] - B. Ramanathan / 1978 / A Quantitative Analysis of Excluded-site Effects for Highly Cooperative Binding Systems / Biopolymers 17 (9) : 2171 ~
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