In the area of soil and groundwater environment, explosives are being highlighted. Therefore establishing the criteria for remedial works and developing the related technology are very important issues in the scope of nationwide research project. This investigation was carried out in military shooting area using explosives and focused on the determination of explosive compounds contents in soil and water. Because the domestic criteria have not established, the contents of explosive compound were compared with ROD(Record of Decision) of US EPA. Totally, 6 of 117 sampling point were contaminated and 4.3% of surface soil (0-10 ㎝) and 1.9% of subsoil (10-30) were contaminated. However, ROD value is too site specific according to site conditions to assess degree of contamination using simple comparison of analytical data with ROD. The results of this investigation are valuable for the selection of candidating sites for future precise investigation and risk assessment.