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자료유형
학술저널
저자정보
辛龍德 (원광대학교) 朱陳榮 (발산공업연구소) 高台憲 (원광대학교)
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대한전기학회 전기학회논문지 전기학회논문지 제57권 제5호
발행연도
2008.5
수록면
808 - 815 (8page)

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The composites were fabricated 61[vol.%] β-SiC and 39[vol.%] TiB₂ powders with the liquid forming additives of 8, 12, 16[wt%] Al₂O₃+Y₂O₃ as a sintering aid by pressureless annealing at 1650[℃] for 4 hours. The present study investigated the influence of the content of Al₂O₃+Y₂O₃ sintering additives on the microstructure, mechanical and electrical properties of the pressureless annealed SiC-TiB₂ electroconductive ceramic composites. Reactions between SiC and transition metal TiB₂ were not observed in the microstructure and the phase analysis of the pressureless annealed SiC-TiB₂ electroconductive ceramic composites. Phase analysis of SiC-TiB₂ composites by XRD revealed mostly of α -SiC(6H), β-SiC(3C), TiB₂, and In Situ YAG(Al?Y₃O₁₂). The relative density of SiC-TiB₂ composites was lowered due to gaseous products of the result of reaction between SiC and Al₂O₃+ Y₂O₃. There is another reason which pressureless annealed temperature 1650[℃] is lower 300-450[℃] than applied pressure sintering temperature 1950-2100[℃]. The relative density, the flexural strength, the Young's modulus and the Vicker's hardness showed the highest value of 82.29[%], 189.5[Mpa], 54.60[Gpa] and 2.84[Gpa] for SiC-TiB₂ composites added with 16[wt%] Al₂O₃+Y₂O₃ additives at room temperature. Abnormal grain growth takes place during phase transformation from β-SiC into α-SiC was correlated with In Situ YAG phase by reaction between Al₂O₃ and Y₂O₃ additive during sintering. The electrical resistivity showed the lowest value of 0.0117[Ω. ㎝] for 16[wt%] Al₂O₃+Y₂O₃ additives at 25[℃]. The electrical resistivity was all negative temperature coefficient resistance (NTCR) in the temperature ranges from 25℃ to 700[℃]. The resistance temperature coefficient of composite showed the lowest value of -2.3×10?³[℃]?¹ for 16[wt%] additives in the temperature ranges from 25[℃] to 100[℃].

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Abstract
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UCI(KEPA) : I410-ECN-0101-2009-560-019045456