지원사업
학술연구/단체지원/교육 등 연구자 활동을 지속하도록 DBpia가 지원하고 있어요.
커뮤니티
연구자들이 자신의 연구와 전문성을 널리 알리고, 새로운 협력의 기회를 만들 수 있는 네트워킹 공간이에요.
초록· 키워드
오류제보하기
The zinc(II) complex, Zn(NCS)₂(C₃H₄N₂S)₂, Ⅰ, has been synthesized and characterized by single crystal X-ray diffraction, thermal analysis and infrared spectroscopy. The complex Ⅰ crystallizes in the triclinic system, P1 space group with α = 7.587(1), b = 8.815(1), c = 12.432(2) A, α= 75.584(8), β= 83.533(9), γ = 68.686(8)°, V = 750.0(2) A³, Z = 2, R₁ = 0.036 and ωR₂ = 0.101. The central Zn(Ⅱ) atom has a tetrahedral coordination geometry, with the heterocyclic nitrogen atoms of 2-aminothiazole ligands and the nitrogen atoms of isothiocyanate ligands. The crystal structure is stabilized by one-dimensional networks of the intermolecular N-H…S hydrogen bonds between the amino group of 2-aminothiazole ligands and the sulfur atom of isothiocyanate ligands. Based on the results of thermal analysis, the thermal decomposition reaction of complex Ⅰ was analyzed to have three distinctive stages such as the loss of 2-aminothiazole, the decomposition of isothiocyanate and the formation of metal oxide.
목차
Abstract
1. Introduction
2. Experimental
3. Results and Discussion
References
참고문헌 (9)
참고문헌 신청
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C. H. Kim, Ph.D. Thesis, The University of Tokyo, Japan (1996).
M. Fujita, “Comprehensive Supramolecular Chemistry”, Vol. 9, p. 253, J. P. Sauvage and M. W. Hosseini, Eds., Pergamon Press, Oxford, U.K. (1996).
D. Braga, F. Grepioni and G. R. Desiraju, Chem. Rev., 98, 1375(1998).
O. M. Yaghi, H. L. Li, C. Davis, D. Richardson and T. L. Groy, Acc. Chem. Res., 31, 474(1998).
C. H. Kim, Ph.D. Thesis, The University of Tokyo, Japan (1996).
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UCI(KEPA) : I410-ECN-0101-2009-433-015204544