지원사업
학술연구/단체지원/교육 등 연구자 활동을 지속하도록 DBpia가 지원하고 있어요.
커뮤니티
연구자들이 자신의 연구와 전문성을 널리 알리고, 새로운 협력의 기회를 만들 수 있는 네트워킹 공간이에요.
초록· 키워드
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Inclusion selectivities of the cyanocadmate host complexes with ammonium oniums, [Cdx(CN)_(2x)][oniumㆍzG] (onium = NMe₃Et^+, NMeEt₃^+ and NEt₄^+, G = guest), have been investigated for C_6H_6 (B), PhMe (T), PhEt (E), ortho (O), meta (M), and para (P) isomers of C_6H₄Me₂as the aromatic guest molecules. From the binary, ternary, quaternary and quinary mixed guests of B, T, E, O, M and P, the order of preference in the NMe₃Et+-host is B≫T＞P≒O≒M and E＞O≫P≒M; in the NMeEt₃^+-host is T＞B＞P≫O≒M and E＞P≫M＞O; in the NEt₄^+-host is B≫T≒O≒M≒P. However, the NEt₄^+-host complexes of E, O, M and P mixed-guests were not obtained. These inclusion selectivities were compared to our previous results of the NMe₄^+-host; T＞B＞P≫M＞O and E＞P≫M＞O.
목차
Abstract
1. Introduction
2. Experimental
3. Results and Discussion
4. Conclusion
References
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UCI(KEPA) : I410-ECN-0101-2009-433-018067776